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@ARTICLE{Gunkel:878684,
author = {Gunkel, F. and Christensen, D. V. and Pryds, N.},
title = {{C}harge-transfer engineering strategies for tailored ionic
conductivity at oxide interfaces},
journal = {Journal of materials chemistry / C Materials for optical
and electronic devices},
volume = {8},
number = {33},
issn = {2050-7534},
address = {London},
publisher = {RSC},
reportid = {FZJ-2020-03002},
pages = {11354 - 11359},
year = {2020},
abstract = {Exploiting the electronic charge-transfer across oxide
interfaces has emerged as a versatile tool to tailor the
electronic and magnetic properties of oxides. Such
charge-transfer concepts have been applied to drive
insulating oxides into metallic states, to trigger magnetism
in non-magnetic oxides, and to render gate-tunable
low-dimensional superconductors. While the richness in the
electronic and magnetic properties of these systems is the
main focus of research, the implications for the ionic
transport at oxide interfaces have not received much
attention so far. In this communication, we propose that
charge-transfer strategies can also be applied to boost
ionic charge carrier concentrations at interfaces by orders
of magnitude. Based on numerical space-charge modeling, we
will illustrate how the ‘p-type’ charge-transfer
predicted between SrO-terminated SrTiO3 and LaAlO3 may
foster 2-dimensional oxygen ion conduction at the interface.
The ion conduction is effectively separated from impurity
dopants, which may allow large concentrations of oxygen
vacancies to be achieved in the absence of trapping
phenomena. The interface promises high ionic conductivity
with nanoscale confinement, potentially allowing the design
of field-tunable ionic devices.},
cin = {PGI-7 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$},
pnm = {524 - Controlling Collective States (POF3-524)},
pid = {G:(DE-HGF)POF3-524},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000563340200003},
doi = {10.1039/D0TC01780A},
url = {https://juser.fz-juelich.de/record/878684},
}