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@ARTICLE{Tsai:878691,
      author       = {Tsai, Chih-Long and Lan, Tu and Dellen, Christian and Ling,
                      Yihan and Ma, Qianli and Fattakhova-Rohlfing, Dina and
                      Guillon, Olivier and Tietz, Frank},
      title        = {{D}endrite-tolerant all-solid-state sodium batteries and an
                      important mechanism of metal self-diffusion},
      journal      = {Journal of power sources},
      volume       = {476},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2020-03009},
      pages        = {228666 -},
      year         = {2020},
      abstract     = {Inhibition of dendrite growth in all-solid-state lithium
                      batteries (ASSLBs) has long been a challenge to the field.In
                      the present study, the conditions for dendrite growth for a
                      similar but less mature technology, all-solid-statesodium
                      batteries (ASSNBs), are investigated. By simply sticking
                      sodium metal to Na3.4Zr2(SiO4)2.4(PO4)0.6(NZSP) ceramic
                      pellets and without applying external pressure during
                      operation, the critical current density ofNa/NZSP/Na
                      symmetric ASSNBs reaches 9 mA cm􀀀 2 at 25 ◦C. The cells
                      can be stably operated at an areal capacityof 5 mAh cm􀀀 2
                      (per half cycle, with 1.0 mA cm􀀀 2) at 25 ◦C for 300 h
                      in a galvanostatic cycling measurementwithout any dendrite
                      formation. The results outperform the existing ASSLBs and
                      ASSNBs, and also gobeyond satisfying the requirements for
                      practical applications. The influence of the high metal
                      self-diffusioncoefficient on the dendritic plating/stripping
                      is regarded as the most likely reason for the high dendrite
                      toleranceof ASSNBs. A mathematical model based on Fick’s
                      second law was applied as a first approximation toillustrate
                      this influence. Full ASSNBs were fabricated with infiltrated
                      Na3V2(PO4)3 (NVP) as the cathode and canbe stably operated
                      with a capacity of 0.60 mAh cm􀀀 2 at high rate of 0.5 mA
                      cm􀀀 2 at room temperature.},
      cin          = {IEK-1},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000582482700022},
      doi          = {10.1016/j.jpowsour.2020.228666},
      url          = {https://juser.fz-juelich.de/record/878691},
}