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000884092 1001_ $$0P:(DE-HGF)0$$aMhanna, Ramona$$b0
000884092 245__ $$aDynamic Heterogeneities in Liquid Mixtures Confined in Nanopores
000884092 260__ $$aWashington, DC$$bSoc.$$c2020
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000884092 520__ $$aBinary liquid mixtures can exhibit nanosegregation, albeit being fully miscible and homogeneous at the macroscopic scale. This tendency can be amplified by geometrical nanoconfinement, leading to remarkable properties. This work investigates the molecular dynamics of tert-butanol (TBA)–toluene (TOL) mixtures confined in silica nanochannels by quasielastic neutron scattering and molecular dynamics simulation. It reveals a decoupling of the molecular motion of each constituent of the binary liquid, which can be followed independently by selective isotopic H/D labeling. We argue that this behavior is the signature of spatially segregated dynamic heterogeneities, which are due to the recently established core–shell nanophase separation induced by mesoporous confinement.
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000884092 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
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000884092 7001_ $$0P:(DE-HGF)0$$aCatrou, Pierre$$b1
000884092 7001_ $$00000-0001-6207-9146$$aDutta, Sujeet$$b2
000884092 7001_ $$0P:(DE-HGF)0$$aLefort, Ronan$$b3
000884092 7001_ $$0P:(DE-HGF)0$$aEssafri, Ilham$$b4
000884092 7001_ $$00000-0003-0877-7968$$aGhoufi, Aziz$$b5
000884092 7001_ $$0P:(DE-Juel1)140457$$aMuthmann, Matthias$$b6
000884092 7001_ $$0P:(DE-Juel1)131056$$aZamponi, Michaela$$b7$$ufzj
000884092 7001_ $$0P:(DE-HGF)0$$aFrick, Bernhard$$b8
000884092 7001_ $$00000-0002-8784-3021$$aMorineau, Denis$$b9$$eCorresponding author
000884092 773__ $$0PERI:(DE-600)2006039-7$$a10.1021/acs.jpcb.0c01035$$gVol. 124, no. 15, p. 3152 - 3162$$n15$$p3152 - 3162$$tThe journal of physical chemistry <Washington, DC> / B$$v124$$x1520-5207$$y2020
000884092 8564_ $$uhttps://juser.fz-juelich.de/record/884092/files/zamponi_Manuscript-MORINEAU-Dynamics-JPC-2020_revised.pdf$$yPublished on 2020-03-27. Available in OpenAccess from 2021-03-27.
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