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000884104 1001_ $$0P:(DE-HGF)0$$aBarrio, Jesús del$$b0$$eCorresponding author
000884104 245__ $$aEmerging Two-Dimensional Crystallization of Cucurbit[8]uril Complexes: From Supramolecular Polymers to Nanofibers
000884104 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2019
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000884104 520__ $$aThe binding of imidazolium salts to cucurbit[8]uril, CB[8], triggers a stepwise self-assembly process with semiflexible polymer chains and crystalline nanostructures as early- and late-stage species, respectively. In such a process, which involves the crystallization of the host–guest complexes, the guest plays a critical role in directing self-assembly toward desirable morphologies. These include platelet-like aggregates and two-dimensional (2D) fibers, which, moreover, exhibit viscoelastic and lyotropic properties. Our observations provide a deeper understanding of the self-assembly of CB[8] complexes, with fundamental implications in the design of functional 2D systems and crystalline materials.
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000884104 7001_ $$0P:(DE-Juel1)180513$$aLiu, Jingjing$$b1$$ufzj
000884104 7001_ $$0P:(DE-HGF)0$$aBrady, Ryan A.$$b2
000884104 7001_ $$0P:(DE-HGF)0$$aTan, Cindy S. Y.$$b3
000884104 7001_ $$00000-0002-8842-9324$$aChiodini, Stefano$$b4
000884104 7001_ $$0P:(DE-HGF)0$$aRicci, Maria$$b5
000884104 7001_ $$0P:(DE-HGF)0$$aFernández-Leiro, Rafael$$b6
000884104 7001_ $$0P:(DE-HGF)0$$aTsai, Ching-Ju$$b7
000884104 7001_ $$0P:(DE-HGF)0$$aVasileiadi, Panagiota$$b8
000884104 7001_ $$00000-0002-1458-9747$$aDi Michele, Lorenzo$$b9
000884104 7001_ $$0P:(DE-HGF)0$$aLairez, Didier$$b10
000884104 7001_ $$0P:(DE-HGF)0$$aToprakcioglu, Chris$$b11
000884104 7001_ $$00000-0001-8032-7166$$aScherman, Oren A.$$b12$$eCorresponding author
000884104 773__ $$0PERI:(DE-600)1472210-0$$a10.1021/jacs.9b07506$$gVol. 141, no. 36, p. 14021 - 14025$$n36$$p14021 - 14025$$tJournal of the American Chemical Society$$v141$$x1520-5126$$y2019
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