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@ARTICLE{Barrio:884104,
author = {Barrio, Jesús del and Liu, Jingjing and Brady, Ryan A. and
Tan, Cindy S. Y. and Chiodini, Stefano and Ricci, Maria and
Fernández-Leiro, Rafael and Tsai, Ching-Ju and Vasileiadi,
Panagiota and Di Michele, Lorenzo and Lairez, Didier and
Toprakcioglu, Chris and Scherman, Oren A.},
title = {{E}merging {T}wo-{D}imensional {C}rystallization of
{C}ucurbit[8]uril {C}omplexes: {F}rom {S}upramolecular
{P}olymers to {N}anofibers},
journal = {Journal of the American Chemical Society},
volume = {141},
number = {36},
issn = {1520-5126},
address = {Washington, DC},
publisher = {American Chemical Society},
reportid = {FZJ-2020-03099},
pages = {14021 - 14025},
year = {2019},
abstract = {The binding of imidazolium salts to cucurbit[8]uril, CB[8],
triggers a stepwise self-assembly process with semiflexible
polymer chains and crystalline nanostructures as early- and
late-stage species, respectively. In such a process, which
involves the crystallization of the host–guest complexes,
the guest plays a critical role in directing self-assembly
toward desirable morphologies. These include platelet-like
aggregates and two-dimensional (2D) fibers, which, moreover,
exhibit viscoelastic and lyotropic properties. Our
observations provide a deeper understanding of the
self-assembly of CB[8] complexes, with fundamental
implications in the design of functional 2D systems and
crystalline materials.},
cin = {JCNS-FRM-II / MLZ / IEK-5},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
I:(DE-Juel1)IEK-5-20101013},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15)},
pid = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:31422657},
UT = {WOS:000486361800002},
doi = {10.1021/jacs.9b07506},
url = {https://juser.fz-juelich.de/record/884104},
}