Hauptseite > Publikationsdatenbank > Emerging Two-Dimensional Crystallization of Cucurbit[8]uril Complexes: From Supramolecular Polymers to Nanofibers > print

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100 1 _ |a Barrio, Jesús del
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245 _ _ |a Emerging Two-Dimensional Crystallization of Cucurbit[8]uril Complexes: From Supramolecular Polymers to Nanofibers
260 _ _ |a Washington, DC
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520 _ _ |a The binding of imidazolium salts to cucurbit[8]uril, CB[8], triggers a stepwise self-assembly process with semiflexible polymer chains and crystalline nanostructures as early- and late-stage species, respectively. In such a process, which involves the crystallization of the host–guest complexes, the guest plays a critical role in directing self-assembly toward desirable morphologies. These include platelet-like aggregates and two-dimensional (2D) fibers, which, moreover, exhibit viscoelastic and lyotropic properties. Our observations provide a deeper understanding of the self-assembly of CB[8] complexes, with fundamental implications in the design of functional 2D systems and crystalline materials.
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700 1 _ |a Tan, Cindy S. Y.
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700 1 _ |a Chiodini, Stefano
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700 1 _ |a Ricci, Maria
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700 1 _ |a Fernández-Leiro, Rafael
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700 1 _ |a Tsai, Ching-Ju
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700 1 _ |a Vasileiadi, Panagiota
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700 1 _ |a Di Michele, Lorenzo
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700 1 _ |a Lairez, Didier
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700 1 _ |a Toprakcioglu, Chris
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700 1 _ |a Scherman, Oren A.
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773 _ _ |a 10.1021/jacs.9b07506
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