%0 Journal Article
%A Ullrich, Patrick
%A Schmauck, Julie
%A Brauns, Marcus
%A Mantel, Marvin
%A Breugst, Martin
%A Pietruszka, Jörg
%T Enantioselective Allylation of Indoles: A Surprising Diastereoselectivity
%J The journal of organic chemistry
%V 85
%N 4
%@ 1520-6904
%C [S.l.]
%I American Chemical Society
%M FZJ-2020-03834
%P 1894 - 1905
%D 2020
%X Herein we show a novel approach toward the allylation of indoles. Thereby, we explore a class of bench-stable allylboronates and fine-tune their reactivity. The allylations of different substituted indoles proceed with negligible diastereo- and excellent enantioselectivities. This surprising selectivity (up to 99:1 er, up to ≈60:40 dr) is rationalized by DFT calculations.
%F PUB:(DE-HGF)16
%9 Journal Article
%$ 31905290
%U <Go to ISI:>//WOS:000516665800012
%R 10.1021/acs.joc.9b02573
%U https://juser.fz-juelich.de/record/885451