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000885451 1001_ $$0P:(DE-Juel1)171936$$aUllrich, Patrick$$b0
000885451 245__ $$aEnantioselective Allylation of Indoles: A Surprising Diastereoselectivity
000885451 260__ $$a[S.l.]$$bAmerican Chemical Society$$c2020
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000885451 520__ $$aHerein we show a novel approach toward the allylation of indoles. Thereby, we explore a class of bench-stable allylboronates and fine-tune their reactivity. The allylations of different substituted indoles proceed with negligible diastereo- and excellent enantioselectivities. This surprising selectivity (up to 99:1 er, up to ≈60:40 dr) is rationalized by DFT calculations.
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000885451 7001_ $$0P:(DE-Juel1)156198$$aBrauns, Marcus$$b2
000885451 7001_ $$0P:(DE-Juel1)166432$$aMantel, Marvin$$b3$$ufzj
000885451 7001_ $$0P:(DE-HGF)0$$aBreugst, Martin$$b4$$eCorresponding author
000885451 7001_ $$0P:(DE-Juel1)128906$$aPietruszka, Jörg$$b5$$eCorresponding author$$ufzj
000885451 773__ $$0PERI:(DE-600)1472273-2$$a10.1021/acs.joc.9b02573$$gVol. 85, no. 4, p. 1894 - 1905$$n4$$p1894 - 1905$$tThe journal of organic chemistry$$v85$$x1520-6904$$y2020
000885451 8564_ $$uhttps://juser.fz-juelich.de/record/885451/files/17-Ullrich_Breugst_Pietruszka-JOC-2019_main_revised.pdf$$yPublished on 2020-01-06. Available in OpenAccess from 2021-01-06.$$zStatID:(DE-HGF)0510
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