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@ARTICLE{Ullrich:885451,
      author       = {Ullrich, Patrick and Schmauck, Julie and Brauns, Marcus and
                      Mantel, Marvin and Breugst, Martin and Pietruszka, Jörg},
      title        = {{E}nantioselective {A}llylation of {I}ndoles: {A}
                      {S}urprising {D}iastereoselectivity},
      journal      = {The journal of organic chemistry},
      volume       = {85},
      number       = {4},
      issn         = {1520-6904},
      address      = {[S.l.]},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2020-03834},
      pages        = {1894 - 1905},
      year         = {2020},
      abstract     = {Herein we show a novel approach toward the allylation of
                      indoles. Thereby, we explore a class of bench-stable
                      allylboronates and fine-tune their reactivity. The
                      allylations of different substituted indoles proceed with
                      negligible diastereo- and excellent enantioselectivities.
                      This surprising selectivity (up to 99:1 er, up to ≈60:40
                      dr) is rationalized by DFT calculations.},
      cin          = {IBOC / IBG-1},
      ddc          = {610},
      cid          = {I:(DE-Juel1)IBOC-20090406 / I:(DE-Juel1)IBG-1-20101118},
      pnm          = {581 - Biotechnology (POF3-581)},
      pid          = {G:(DE-HGF)POF3-581},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {31905290},
      UT           = {WOS:000516665800012},
      doi          = {10.1021/acs.joc.9b02573},
      url          = {https://juser.fz-juelich.de/record/885451},
}