Home > Publications database > Enantioselective Allylation of Indoles: A Surprising Diastereoselectivity > print

001     885451
005     20210208142315.0
024 7 _ |a 10.1021/acs.joc.9b02573
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024 7 _ |a 1520-6904
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100 1 _ |a Ullrich, Patrick
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245 _ _ |a Enantioselective Allylation of Indoles: A Surprising Diastereoselectivity
260 _ _ |a [S.l.]
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520 _ _ |a Herein we show a novel approach toward the allylation of indoles. Thereby, we explore a class of bench-stable allylboronates and fine-tune their reactivity. The allylations of different substituted indoles proceed with negligible diastereo- and excellent enantioselectivities. This surprising selectivity (up to 99:1 er, up to ≈60:40 dr) is rationalized by DFT calculations.
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700 1 _ |a Schmauck, Julie
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700 1 _ |a Brauns, Marcus
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700 1 _ |a Mantel, Marvin
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700 1 _ |a Breugst, Martin
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700 1 _ |a Pietruszka, Jörg
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773 _ _ |a 10.1021/acs.joc.9b02573
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|t The journal of organic chemistry
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|y 2020
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856 4 _ |y Published on 2020-01-06. Available in OpenAccess from 2021-01-06.
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|u https://juser.fz-juelich.de/record/885451/files/17-Ullrich_Breugst_Pietruszka-JOC-2019_main_revised.pdf
856 4 _ |u https://juser.fz-juelich.de/record/885451/files/acs.joc.9b02573.pdf
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