000885452 001__ 885452
000885452 005__ 20210130010411.0
000885452 0247_ $$2doi$$a10.1002/chem.202000664
000885452 0247_ $$2ISSN$$a0947-6539
000885452 0247_ $$2ISSN$$a1521-3765
000885452 0247_ $$2Handle$$a2128/25836
000885452 0247_ $$2altmetric$$aaltmetric:82269651
000885452 0247_ $$2pmid$$apmid:32104930
000885452 0247_ $$2WOS$$aWOS:000533570100001
000885452 037__ $$aFZJ-2020-03835
000885452 041__ $$aEnglish
000885452 082__ $$a540
000885452 1001_ $$0P:(DE-HGF)0$$aPaul, Melanie$$b0
000885452 245__ $$aExceptional Substrate Diversity in Oxygenation Reactions Catalyzed by a Bis(μ‐oxo) Copper Complex
000885452 260__ $$aWeinheim$$bWiley-VCH$$c2020
000885452 3367_ $$2DRIVER$$aarticle
000885452 3367_ $$2DataCite$$aOutput Types/Journal article
000885452 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1601990766_2081
000885452 3367_ $$2BibTeX$$aARTICLE
000885452 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000885452 3367_ $$00$$2EndNote$$aJournal Article
000885452 520__ $$aThe enzyme tyrosinase contains a reactive side‐on peroxo dicopper(II) center as catalytically active species in C−H oxygenation reactions. The tyrosinase activity of the isomeric bis(μ‐oxo) dicopper(III) form has been discussed controversially. The synthesis of bis(μ‐oxo) dicopper(III) species [Cu2(μ‐O)2(L1)2](X)2 ([O1](X)2, X=PF6−, BF4−, OTf−, ClO4−), stabilized by the new hybrid guanidine ligand 2‐{2‐((dimethylamino)methyl)phenyl}‐1,1,3,3‐tetramethylguanidine (L1), and its characterization by UV/Vis, Raman, and XAS spectroscopy, as well as cryo‐UHR‐ESI mass spectrometry, is described. We highlight selective oxygenation of a plethora of phenolic substrates mediated by [O1](PF6)2, which results in mono‐ and bicyclic quinones and provides an attractive strategy for designing new phenazines. The selectivity is predicted by using the Fukui function, which is hereby introduced into tyrosinase model chemistry. Our bioinspired catalysis harnesses molecular dioxygen for organic transformations and achieves a substrate diversity reaching far beyond the scope of the enzyme.
000885452 536__ $$0G:(DE-HGF)POF3-581$$a581 - Biotechnology (POF3-581)$$cPOF3-581$$fPOF III$$x0
000885452 588__ $$aDataset connected to CrossRef
000885452 7001_ $$0P:(DE-HGF)0$$aTeubner, Melissa$$b1
000885452 7001_ $$0P:(DE-HGF)0$$aGrimm‐Lebsanft, Benjamin$$b2
000885452 7001_ $$0P:(DE-HGF)0$$aGolchert, Christiane$$b3
000885452 7001_ $$0P:(DE-HGF)0$$aMeiners, Yannick$$b4
000885452 7001_ $$0P:(DE-HGF)0$$aSenft, Laura$$b5
000885452 7001_ $$0P:(DE-HGF)0$$aKeisers, Kristina$$b6
000885452 7001_ $$0P:(DE-HGF)0$$aLiebhäuser, Patricia$$b7
000885452 7001_ $$0P:(DE-HGF)0$$aRösener, Thomas$$b8
000885452 7001_ $$0P:(DE-HGF)0$$aBiebl, Florian$$b9
000885452 7001_ $$0P:(DE-HGF)0$$aBuchenau, Sören$$b10
000885452 7001_ $$0P:(DE-HGF)0$$aNaumova, Maria$$b11
000885452 7001_ $$0P:(DE-HGF)0$$aMurzin, Vadim$$b12
000885452 7001_ $$0P:(DE-HGF)0$$aKrug, Roxanne$$b13
000885452 7001_ $$0P:(DE-HGF)0$$aHoffmann, Alexander$$b14
000885452 7001_ $$0P:(DE-Juel1)128906$$aPietruszka, Jörg$$b15$$ufzj
000885452 7001_ $$0P:(DE-HGF)0$$aIvanović‐Burmazović, Ivana$$b16
000885452 7001_ $$0P:(DE-HGF)0$$aRübhausen, Michael$$b17
000885452 7001_ $$0P:(DE-HGF)0$$aHerres‐Pawlis, Sonja$$b18$$eCorresponding author
000885452 773__ $$0PERI:(DE-600)1478547-x$$a10.1002/chem.202000664$$gVol. 26, no. 34, p. 7556 - 7562$$n34$$p7556 - 7562$$tChemistry - a European journal$$v26$$x1521-3765$$y2020
000885452 8564_ $$uhttps://juser.fz-juelich.de/record/885452/files/chem.202000664.pdf$$yOpenAccess
000885452 8564_ $$uhttps://juser.fz-juelich.de/record/885452/files/chem.202000664.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000885452 909CO $$ooai:juser.fz-juelich.de:885452$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b0$$kRWTH
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b1$$kRWTH
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Universität Hamburg$$b1
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Universität Hamburg$$b2
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b3$$kRWTH
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b4$$kRWTH
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Friedrich-Alexander-Universität Erlangen-Nürnberg$$b5
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b6$$kRWTH
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b7$$kRWTH
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b8$$kRWTH
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Universität Hamburg$$b9
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Universität Hamburg$$b10
000885452 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-HGF)0$$aDeutsches Elektronen-Synchrotron$$b11$$kDESY
000885452 9101_ $$0I:(DE-588b)2008985-5$$6P:(DE-HGF)0$$aDeutsches Elektronen-Synchrotron$$b12$$kDESY
000885452 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-HGF)0$$aForschungszentrum Jülich$$b13$$kFZJ
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Heinrich-Heine-Universität Düsseldorf$$b13
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b14$$kRWTH
000885452 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)128906$$aForschungszentrum Jülich$$b15$$kFZJ
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-Juel1)128906$$a Heinrich-Heine-Universität Düsseldorf$$b15
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Friedrich-Alexander-Universität Erlangen-Nürnberg$$b16
000885452 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Universität Hamburg$$b17
000885452 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b18$$kRWTH
000885452 9131_ $$0G:(DE-HGF)POF3-581$$1G:(DE-HGF)POF3-580$$2G:(DE-HGF)POF3-500$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bKey Technologies$$lKey Technologies for the Bioeconomy$$vBiotechnology$$x0
000885452 9141_ $$y2020
000885452 915__ $$0StatID:(DE-HGF)1210$$2StatID$$aDBCoverage$$bIndex Chemicus$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2020-02-26
000885452 915__ $$0LIC:(DE-HGF)CCBYNCND4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0
000885452 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bCHEM-EUR J : 2018$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bCHEM-EUR J : 2018$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2020-02-26$$wger
000885452 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000885452 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)1200$$2StatID$$aDBCoverage$$bChemical Reactions$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0310$$2StatID$$aDBCoverage$$bNCBI Molecular Biology Database$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2020-02-26
000885452 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2020-02-26$$wger
000885452 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-02-26
000885452 920__ $$lno
000885452 9201_ $$0I:(DE-Juel1)IBOC-20090406$$kIBOC$$lInstitut für Bioorganische Chemie (HHUD)$$x0
000885452 9201_ $$0I:(DE-Juel1)IBG-1-20101118$$kIBG-1$$lBiotechnologie$$x1
000885452 980__ $$ajournal
000885452 980__ $$aVDB
000885452 980__ $$aUNRESTRICTED
000885452 980__ $$aI:(DE-Juel1)IBOC-20090406
000885452 980__ $$aI:(DE-Juel1)IBG-1-20101118
000885452 9801_ $$aFullTexts