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@ARTICLE{Kim:885498,
      author       = {Kim, Un-Hyuck and Park, Geon-Tae and Son, Byoung-Ki and
                      Nam, Gyeong Won and Liu, Jun and Kuo, Liang-Yin and
                      Kaghazchi, Payam and Yoon, Chong S. and Sun, Yang-Kook},
      title        = {{H}euristic solution for achieving long-term cycle
                      stability for {N}i-rich layered cathodes at full depth of
                      discharge},
      journal      = {Nature energy},
      volume       = {5},
      issn         = {2058-7546},
      address      = {London},
      publisher    = {Nature Publishing Group},
      reportid     = {FZJ-2020-03879},
      pages        = {860},
      year         = {2020},
      abstract     = {The demand for energy sources with high energy densities
                      continues to push the limits of Ni-rich layered oxides,
                      which are currently the most promising cathode materials in
                      automobile batteries. Although most current research is
                      focused on extending battery life using Ni-rich layered
                      cathodes, long-term cycling stability using a full cell is
                      yet to be demonstrated. Here, we introduce
                      Li[Ni0.90Co0.09Ta0.01]O2, which exhibits $90\%$ capacity
                      retention after 2,000 cycles at full depth of discharge
                      (DOD) and a cathode energy density >850 Wh kg−1. In
                      contrast, the currently most sought-after
                      Li[Ni0.90Co0.09Al0.01]O2 cathode loses $~40\%$ of its
                      initial capacity within 500 cycles at full DOD. Cycling
                      stability is achieved by radially aligned primary particles
                      with [003] crystallographic texture that effectively
                      dissipate the internal strain occurring in the deeply
                      charged state, while the substitution of Ni3+ with higher
                      valence ions induces ordered occupation of Ni ions in the Li
                      slab and stabilizes the delithiated structure.},
      cin          = {IEK-1},
      ddc          = {330},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000571739400005},
      doi          = {10.1038/s41560-020-00693-6},
      url          = {https://juser.fz-juelich.de/record/885498},
}