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037 _ _ |a FZJ-2020-03937
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082 _ _ |a 530
100 1 _ |a Paul, N.
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245 _ _ |a Combining SANS and VSANS to Extend Q-Range for Morphology Investigation of Silicon-Graphite Anodes
260 _ _ |a New York, NY
|c 2020
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520 _ _ |a Silicon-based electrodes are attractive candidates as anodes for Li-ion batteries due to their high theoretical specific capacity. However, repeated lithiation/delithiation causes significant morphological changes of the silicon particles which results in formation of highly porous silicon structures and severe side reactions at the silicon/electrolyte interface. To quantify such morphological changes in the micrometer as well as on the nanometer scale, we combine very small-angle neutron scattering (VSANS) and small-angle neutron scattering (SANS) techniques. While conventional and contrast-matched SANS data provide insights into the solid-electrolyte-interphase (SEI) coverage around the silicon particles and filling of the evolving porosity within the electrode, VSANS data provide information on the micrometer-sized graphite particles.
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693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
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693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
|e SANS-1: Small angle neutron scattering
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700 1 _ |a Frielinghaus, H.
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700 1 _ |a Busch, Sebastian
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700 1 _ |a Pipich, V.
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700 1 _ |a Gilles, R.
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773 _ _ |a 10.1134/S1027451020070368
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|t Surface investigation, x-ray, synchrotron and neutron techniques
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