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@ARTICLE{Zhou:885681,
author = {Zhou, Lei and Danilov, Dmitri L. and Eichel, Rüdiger‐A.
and Notten, Peter H. L.},
title = {{H}ost {M}aterials {A}nchoring {P}olysulfides in {L}i–{S}
{B}atteries {R}eviewed},
journal = {Advanced energy materials},
volume = {11},
number = {15},
issn = {1614-6840},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2020-04012},
pages = {2001304},
year = {2021},
abstract = {Lithium–sulfur batteries (Li–S) have become a viable
alternative to future energy storage devices. The
electrochemical reaction based on lithium and sulfur
promises an extraordinary theoretical energy density, which
is far higher than current commercialized Li‐ion
batteries. However, the principal disadvantage impeding the
success of Li–S batteries lies in the severe leakage and
migration of soluble lithium polysulfide intermediates out
of cathodes upon cycling. The loss of active sulfur species
incurs significant capacity decay and poor battery
lifespans. Considerable efforts have been devoted to
developing various sulfur host materials that can
effectively anchor lithium polysulfides. Herein, a
comprehensive review is presented of recent advances in
sulfur host materials. On the basis of the electrochemistry
of Li–S batteries, the strategies for anchoring
polysulfides are systematically categorized into physical
confinement and chemical bonding. The structural merits of
various sulfur host materials are highlighted, and the
interaction mechanisms with sulfur species are discussed in
detail, which provides valuable insights into the rational
design and engineering of advanced sulfur host materials
facilitating the commercialization of Li–S batteries.
Future challenges and promising research prospects for
sulfur host materials are proposed at the end of the
review.},
cin = {IEK-9},
ddc = {050},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {899 - ohne Topic (POF4-899)},
pid = {G:(DE-HGF)POF4-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000544093800001},
doi = {10.1002/aenm.202001304},
url = {https://juser.fz-juelich.de/record/885681},
}