% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Matse:885753,
      author       = {Matse, Mpumelelo and Berg, Peter and Eikerling, Michael},
      title        = {{A}symmetric double-layer charging in a cylindrical
                      nanopore under closed confinement},
      journal      = {The journal of chemical physics},
      volume       = {152},
      number       = {8},
      issn         = {1089-7690},
      address      = {Melville, NY},
      publisher    = {American Institute of Physics},
      reportid     = {FZJ-2020-04065},
      pages        = {084103 -},
      year         = {2020},
      abstract     = {This article presents a physical–mathematical treatment
                      and numerical simulations of electric double layer charging
                      in a closed, finite, and cylindrical nanopore of circular
                      cross section, embedded in a polymeric host with charged
                      walls and sealed at both ends by metal electrodes under an
                      external voltage bias. Modified Poisson–Nernst–Planck
                      equations were used to account for finite ion sizes, subject
                      to an electroneutrality condition. The time evolution of the
                      formation and relaxation of the double layers was explored.
                      Moreover, equilibrium ion distributions and differential
                      capacitance curves were investigated as functions of the
                      pore surface charge density, electrolyte concentration, ion
                      sizes, and pore size. Asymmetric properties of the
                      differential capacitance curves reveal that the structure of
                      the double layer near each electrode is controlled by the
                      charge concentration along the pore surface and by charge
                      asymmetry in the electrolyte. These results carry
                      implications for accurately simulating cylindrical
                      capacitors and electroactuators.},
      cin          = {IEK-13},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-13-20190226},
      pnm          = {113 - Methods and Concepts for Material Development
                      (POF3-113)},
      pid          = {G:(DE-HGF)POF3-113},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:32113335},
      UT           = {WOS:000519832600003},
      doi          = {10.1063/1.5139541},
      url          = {https://juser.fz-juelich.de/record/885753},
}