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@ARTICLE{BussmannHolder:885930,
author = {Bussmann-Holder, Annette and Keller, Hugo and Simon, Arndt
and Bihlmayer, Gustav and Roleder, Krystian and Szot,
Krzysztof},
title = {{U}nconventional {C}o-{E}xistence of {I}nsulating
{N}ano-{R}egions and {C}onducting {F}ilaments in {R}educed
{S}r{T}i{O}3: {M}ode {S}oftening, {L}ocal
{P}iezoelectricity, and {M}etallicity},
journal = {Crystals},
volume = {10},
number = {6},
issn = {2073-4352},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2020-04186},
pages = {437},
year = {2020},
abstract = {Doped SrTiO3 becomes a metal at extremely low doping
concentrations n and is even superconducting at n < 1020
cm−3, with the superconducting transition temperature
adopting a dome-like shape with increasing carrier
concentration. In this paper it is shown within the
polarizability model and from first principles calculations
that up to a well-defined carrier concentration nc
transverse optic mode softening takes place together with
polar nano-domain formation, which provides evidence of
inhomogeneity and a two-component type behavior with
metallicity coexisting with polarity. Beyond this region, a
conventional metal is formed where superconductivity as well
as mode softening is absent. For n ≤ nc the effective
electron-phonon coupling follows the superconducting
transition temperature. Effusion measurements, as well as
macroscopic and nanoscopic conductivity measurements,
indicate that the distribution of oxygen vacancies is local
and inhomogeneous, from which it is concluded that
metallicity stems from filaments which are embedded in a
polar matrix as long as n ≤ nc.},
cin = {PGI-1 / IAS-1 / JARA-FIT / JARA-HPC},
ddc = {540},
cid = {I:(DE-Juel1)PGI-1-20110106 / I:(DE-Juel1)IAS-1-20090406 /
$I:(DE-82)080009_20140620$ / $I:(DE-82)080012_20140620$},
pnm = {142 - Controlling Spin-Based Phenomena (POF3-142) / 143 -
Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000554685500001},
doi = {10.3390/cryst10060437},
url = {https://juser.fz-juelich.de/record/885930},
}