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@ARTICLE{Scotti:886097,
author = {Scotti, A. and Houston, J. E. and Brugnoni, M. and Schmidt,
M. M. and Schulte, M. F. and Bochenek, S. and Schweins, R.
and Feoktystov, A. and Radulescu, A. and Richtering, W.},
title = {{P}hase behavior of ultrasoft spheres show stable bcc
lattices},
journal = {Physical review / E},
volume = {102},
number = {5},
issn = {2470-0045},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {FZJ-2020-04265},
pages = {052602},
year = {2020},
abstract = {The phase behavior of supersoft spheres is explored using
solutions of ultralow cross-linked
poly(N-isopropylacrylamide)-based microgels as a model
system. For these microgels, the effects of the electric
charges on their surfaces can be neglected and therefore
only the role of softness on the phase behavior is
investigated. The samples show a liquid-to-crystal
transition at higher volume fraction with respect to both
hard spheres and stiffer microgels. Furthermore, stable body
centered cubic (bcc) crystals are observed in addition to
the expected face centered cubic (fcc) crystals. Small-angle
x-ray and neutron scattering with contrast variation allow
the characterization of both the microgel-to-microgel
distance and the architecture of single microgels in crowded
solutions. The measurements reveal that the stable bcc
crystals depend on the interplay between the collapse and
the interpenetration of the external shell of the ultralow
cross-linked microgels.},
cin = {JCNS-FRM-II / JCNS-1 / JCNS-2 / MLZ},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-2-20110106 /
I:(DE-588b)4597118-3},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15)},
pid = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
experiment = {EXP:(DE-MLZ)KWS1-20140101 / EXP:(DE-MLZ)KWS2-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000583695400008},
doi = {10.1103/PhysRevE.102.052602},
url = {https://juser.fz-juelich.de/record/886097},
}