TY  - JOUR
AU  - Hanbali, Ghadir
AU  - Jodeh, Shehdeh
AU  - Hamed, Othman
AU  - Bol, Roland
AU  - Khalaf, Bayan
AU  - Qdemat, Asma
AU  - Samhan, Subhi
AU  - Dagdag, Omar
TI  - Magnetic Multiwall Carbon Nanotube Decorated with Novel Functionalities: Synthesis and Application as Adsorbents for Lead Removal from Aqueous Medium
JO  - Processes
VL  - 8
IS  - 8
SN  - 2227-9717
CY  - Basel
PB  - MDPI
M1  - FZJ-2020-04357
SP  - 986 -
PY  - 2020
AB  - Water pollution is one of the major challenges facing modern society because of industrial development and urban growth. This study is directed towards assessing the use of multiwall carbon nanotube, after derivatization and magnetization, as a new and renewable absorbent, to remove toxic metal ions from waste streams. The adsorbents were prepared by, first oxidation of multiwall carbon nanotube, then derivatizing the oxidized product with hydroxyl amine, hydrazine and amino acid. The adsorbents were characterized by various techniques. The adsorption efficiency of the multiwall carbon nanotube adsorbents toward Pb(II) was investigated. The effect of adsorbent’s dose, temperature, pH, and time on the adsorption efficiency were studied and the adsorption parameters that gave the highest efficiency were determined. The derivatives have unique coordination sites that included amine, hydroxyl, and carboxyl groups, which are excellent chelating agents for metal ions. The thermodynamic and kinetic results analysis results indicated spontaneous adsorption of Pb(II) by the multiwall carbon nanotube adsorbents at room temperature. The adsorption process followed pseudo-second-order and Langmuir isotherm model. The adsorbents were regenerated using 0.1 N HCl.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000568117500001
DO  - DOI:10.3390/pr8080986
UR  - https://juser.fz-juelich.de/record/887700
ER  -