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@ARTICLE{Rheinheimer:887813,
author = {Rheinheimer, Wolfgang and Blendell, John E. and Handwerker,
Carol A.},
title = {{E}quilibrium and kinetic shapes of grains in polycrystals},
journal = {Acta materialia},
volume = {191},
issn = {1359-6454},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2020-04439},
pages = {101 - 110},
year = {2020},
abstract = {The equilibrium crystal shape is a convex shape bound by
the lowest energy interfaces. In many polycrystalline
microstructures created by grain growth, the observed
distribution of grain boundary planes appears to be
dominated at low driving forces (after long grain growth
times) by the planes present in the equilibrium crystal
shape. However, at earlier stages of grain growth, it is
expected that kinetic effects will play an important role in
grain boundary motion and morphology. Analogous to the
equilibrium crystal shape, the kinetic crystal shape of seed
crystals growing from a liquid at higher supersaturations is
bound by the slowest growing orientations. This study
presents an equivalent construction for grain boundaries in
polycrystals and uses it to determine the kinetic crystal
shape for strontium titanate as a function of temperature.
Relative grain boundary mobilities for strontium titanate
for the low energy crystallographic orientations from seeded
polycrystal experiments are used to calculate the kinetic
crystal shapes as a function of temperature and annealing
atmosphere. The kinetic crystal shapes are then compared to
the morphologies and orientations of the interfaces of the
growing seed crystals, and to the equilibrium crystal
shapes, as wel},
cin = {IEK-1},
ddc = {670},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000533619700009},
doi = {10.1016/j.actamat.2020.03.055},
url = {https://juser.fz-juelich.de/record/887813},
}