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@ARTICLE{Leonhard:887823,
author = {Leonhard, Tobias and Schulz, Alexander D. and Röhm, Holger
and Wagner, Susanne and Altermann, Fabian J. and
Rheinheimer, Wolfgang and Hoffmann, Michael J. and Colsmann,
Alexander},
title = {{P}robing the {M}icrostructure of {M}ethylammonium {L}ead
{I}odide {P}erovskite {S}olar {C}ells},
journal = {Energy technology},
volume = {7},
number = {3},
issn = {2194-4296},
address = {Weinheim [u.a.]},
publisher = {Wiley-VCH},
reportid = {FZJ-2020-04449},
pages = {1800989 -},
year = {2019},
abstract = {The microstructure of absorber layers is pivotally
important for all thin‐film solar technologies. Using
electron backscattered diffraction (EBSD), the crystal
orientation in methylammonium lead iodide thin films with
submicrometer resolution is reported. For the vast majority
of (110) oriented grains, the c‐axis of the perovskite
unit cell is oriented in‐plane. Although some adjacent
grains exhibit the same in‐plane horizontal orientation of
the c‐axis, no universal horizontal orientation of the
c‐axis within the sample plane exists. The (110) crystal
orientation correlates with an in‐plane orientation of the
ferroelectric polarization as investigated by vertical and
lateral piezoresponse force microscopy (PFM). The individual
grains with different crystal orientations that exhibit
different ferroelectric patterns and surface potentials are
identified. The strong correlation between crystal
orientation and ferroelectric polarization allows
conclusions to be drawn about the microstructure from PFM
measurements and, likewise, the ferroelectric polarization
to be derived from crystallographic observations by EBSD.},
cin = {IEK-1},
ddc = {620},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000462449500019},
doi = {10.1002/ente.201800989},
url = {https://juser.fz-juelich.de/record/887823},
}