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@ARTICLE{Rheinheimer:887839,
author = {Rheinheimer, Wolfgang and Fülling, Manuel and Hoffmann,
Michael J.},
title = {{G}rain growth in weak electric fields in strontium
titanate: {G}rain growth acceleration by defect
redistribution},
journal = {Journal of the European Ceramic Society},
volume = {36},
number = {11},
issn = {0955-2219},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2020-04465},
pages = {2773 - 2780},
year = {2016},
abstract = {The impact of DC electric fields on grain growth in
strontium titanate is investigated between 1350 °C and 1550
°C for fields of up to 50 V/mm. To prevent joule heating by
electrical currents, insulating Al2O3 plates separate
electrodes from samples. The seeded polycrystal technique is
used, which allows evaluating gradients induced by electric
fields. The growth direction of the single crystalline seeds
is perpendicular to the electric field; hence electrostatic
forces do not influence its growth. Below 1425 °C, the
influence of electric fields is very weak. Above 1425 °C
the field results in an increase of the grain boundary
mobility at the negative electrode.The enhancement of the
boundary mobility at the negative electrode is attributed to
electric field induced defect redistribution. Oxygen
vacancies migrate towards the negative electrode, while
strontium vacancies accumulate at the positive electrode.
This defect redistribution is connected to the defect
chemistry dependent grain growth in strontium titanate.},
cin = {IEK-1},
ddc = {660},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000376808100016},
doi = {10.1016/j.jeurceramsoc.2016.04.033},
url = {https://juser.fz-juelich.de/record/887839},
}