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@ARTICLE{Rheinheimer:887842,
author = {Rheinheimer, Wolfgang and Bäurer, Michael and Chien, Harry
and Rohrer, Gregory S. and Handwerker, Carol A. and
Blendell, John E. and Hoffmann, Michael J.},
title = {{T}he equilibrium crystal shape of strontium titanate and
its relationship to the grain boundary plane distribution},
journal = {Acta materialia},
volume = {82},
issn = {1359-6454},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2020-04468},
pages = {32 - 40},
year = {2015},
abstract = {In this study, the equilibrium crystal shape (ECS) of a
model system, strontium titanate, is compared with the grain
boundary plane distribution (GBPD) as a function of
temperature. Strontium titanate has a pronounced surface
energy anisotropy and a grain growth anomaly, with the grain
growth rate decreasing by orders of magnitude with
increasing temperature. The ECS was determined from the
shape of small intragranular pores and the GBPD was
determined from orientation measurements on surfaces, with
the relative areas of grain boundary planes in a polycrystal
correlated to the surface energy of both adjacent crystal
planes. The grain boundary energy has been previously
proposed to be the sum of the surface energy of the adjacent
grains less a binding energy that is assumed to be constant.
While much experimental evidence exists for this assumption
at a fixed temperature, the influence of temperature is not
known. While the anisotropy of the ECS was found to decrease
with temperature, the anisotropy of the GBPD increased with
temperature. These findings indicate that changes in the
binding energy with temperature must be considered, as the
binding energy links the surface energy to the grain
boundary energy. The results are discussed with respect to
the grain growth anomaly of strontium titanate, in which the
grain growth decreases with increasing temperature.},
cin = {IEK-1},
ddc = {670},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000347017800004},
doi = {10.1016/j.actamat.2014.08.065},
url = {https://juser.fz-juelich.de/record/887842},
}