000887897 001__ 887897 000887897 005__ 20220224125212.0 000887897 0247_ $$2doi$$a10.1021/acs.macromol.9b02239 000887897 0247_ $$2Handle$$a2128/30522 000887897 0247_ $$2WOS$$aWOS:000526399500037 000887897 037__ $$aFZJ-2020-04503 000887897 041__ $$aEnglish 000887897 082__ $$a540 000887897 1001_ $$0P:(DE-Juel1)168105$$aLang, Christian$$b0$$eCorresponding author$$ufzj 000887897 245__ $$aShear Flow Behavior of Bidisperse Rodlike Colloids 000887897 260__ $$aWashington, DC$$bSoc.$$c2020 000887897 3367_ $$2DRIVER$$aarticle 000887897 3367_ $$2DataCite$$aOutput Types/Journal article 000887897 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1643034559_6536 000887897 3367_ $$2BibTeX$$aARTICLE 000887897 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000887897 3367_ $$00$$2EndNote$$aJournal Article 000887897 520__ $$aA priori prediction of the flow properties ofpolydisperse rodlike macromolecules is a prerequisite for theunderstanding of many industrial and biological processes. Usingmixtures of two naturally monodisperse viruses, we create abenchmark bidisperse suspension of rodlike colloids to test theeffect of length bidispersity on the shear flow behavior. We findthat the zero-shear viscosity is a nonlinear function of the fractionof long rods because of the strong length dependence of therotational dynamics, which determine this quantity. Withincreasing concentration and fraction of long rods, the shearthinning gets more pronounced, following the predictions of ourrecently proposed theory which we extended for bidisperse mixtures. This theory allows for a quantitative prediction of the flow properties of bi- and polydisperse mixtures of ideal rods at least for moderate polydispersity. 000887897 536__ $$0G:(DE-HGF)POF4-6G4$$a6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ) (POF4-6G4)$$cPOF4-6G4$$fPOF IV$$x0 000887897 536__ $$0G:(DE-HGF)POF4-632$$a632 - Materials – Quantum, Complex and Functional Materials (POF4-632)$$cPOF4-632$$fPOF IV$$x1 000887897 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0 000887897 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and Proteins$$x0 000887897 693__ $$0EXP:(DE-MLZ)NOSPEC-20140101$$5EXP:(DE-MLZ)NOSPEC-20140101$$eNo specific instrument$$x0 000887897 7001_ $$0P:(DE-Juel1)130797$$aLettinga, M.P.$$b1$$ufzj 000887897 773__ $$0PERI:(DE-600)1491942-4$$a10.1021/acs.macromol.9b02239$$n7$$p2662-2668$$tMacromolecules$$v53$$x0024-9297$$y2020 000887897 8564_ $$uhttps://juser.fz-juelich.de/record/887897/files/acs.macromol.9b02239.pdf 000887897 8564_ $$uhttps://juser.fz-juelich.de/record/887897/files/ReSubmission2.pdf$$yPublished on 2020-03-20. 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