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@ARTICLE{Menzler:887927,
author = {Menzler, Norbert H. and Fang, Qingping},
title = {{M}ultiple charging/discharging cycles of a rechargeable
oxide battery – {E}lectrochemistry and post-test analysis},
journal = {Journal of power sources advances},
volume = {6},
issn = {2666-2485},
address = {[Amsterdam]},
publisher = {Elsevier ScienceDirect},
reportid = {FZJ-2020-04519},
pages = {100041},
year = {2020},
abstract = {A two-layer rechargeable oxide battery using a stack
initially developed for solid oxide cells was operated for
2100 h with more than 1000 charging/discharging cycles.
The operation temperature was 800 °C and the applied
current density (on the solid oxide cell) was
150 mA cm−2. During operation, no electrochemical
indications for degradation were measured. The voltages
achieved during redox cycling were in good agreement with
the equilibrium voltages of the envisaged corresponding
phases. For the first time, a storage material based on the
calcium–iron oxide with the richest iron content was used.
Storage utilization was $86\%,$ thereby reaching a capacity
of 20.6 Ah per layer. Post-test analysis of the storage
revealed mostly expected storage phases and sufficient
remaining storage porosity.},
cin = {IEK-1 / IEK-14},
ddc = {621.3},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-14-20191129},
pnm = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000658488500009},
doi = {10.1016/j.powera.2020.100041},
url = {https://juser.fz-juelich.de/record/887927},
}