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000888127 1001_ $$0P:(DE-Juel1)162347$$aSchmitz-Antoniak, Carolin$$b0$$eCorresponding author
000888127 245__ $$aSensing alterations of the local environment of 3d, 4d, and 4f central ions in polyoxopalladates with soft X-ray magnetic dichroisms
000888127 260__ $$aAmsterdam$$bNorth-Holland Publ. Co.$$c2020
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000888127 520__ $$aPolyoxopalladates hosting 3d, 4d or 4f central ions form a new class of molecular materials with well-defined, tunable morphology and ions coordination to be considered as model systems for basic research. We investigated the isotropic X-ray absorption near-edge structure (XANES), X-ray magnetic circular dichroism (XMCD), and X-ray magnetic linear dichroism (XMLD) to monitor the influence of symmetry changes on electronic and magnetic properties. After a brief introductory review about recent results on 3d and 4d transition metal ions, we (i) show that a change of the coordination symmetry from cubic eightfold (tetrahedral) to sixfold (octahedral) reduces the magnetic moment of Co2+ significantly and (ii) investigate whether axial distortions can modify the 4f states of trivalent lanthanide ions. While for Gd3+ there is no effect visible within experimental uncertainties, changes were observed for Dy3+ and Ho3+. The results are compared to atomic multiplet calculations including the intra-atomic spin-dipole term . Furthermore, several experimental pitfalls are discussed that may lead to misinterpretation of X-ray absorption data but can be excluded in the present study.
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000888127 7001_ $$0P:(DE-Juel1)157892$$aIzarova, Natalya V.$$b1
000888127 7001_ $$0P:(DE-Juel1)166520$$aStuckart, Maria$$b2
000888127 7001_ $$0P:(DE-Juel1)166560$$aSmekhova, Alevtina$$b3
000888127 7001_ $$0P:(DE-HGF)0$$aSchmitz, Detlef$$b4
000888127 7001_ $$0P:(DE-HGF)0$$aShams, S. Fatemeh$$b5
000888127 7001_ $$0P:(DE-HGF)0$$aSiemensmeyer, Konrad$$b6
000888127 7001_ $$0P:(DE-Juel1)4744$$aGiesen, Margret$$b7
000888127 7001_ $$0P:(DE-Juel1)130782$$aKögerler, Paul$$b8
000888127 773__ $$0PERI:(DE-600)1479000-2$$a10.1016/j.jmmm.2020.167063$$gVol. 514, p. 167063 -$$p167063 -$$tJournal of magnetism and magnetic materials$$v514$$x0304-8853$$y2020
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