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| Hauptseite > Publikationsdatenbank > Sensing alterations of the local environment of 3d, 4d, and 4f central ions in polyoxopalladates with soft X-ray magnetic dichroisms > print |
| Hauptseite > Publikationsdatenbank > Sensing alterations of the local environment of 3d, 4d, and 4f central ions in polyoxopalladates with soft X-ray magnetic dichroisms > print |
| 001 | 888127 | ||
| 005 | 20210208142340.0 | ||
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| 100 | 1 | _ | |a Schmitz-Antoniak, Carolin |0 P:(DE-Juel1)162347 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Sensing alterations of the local environment of 3d, 4d, and 4f central ions in polyoxopalladates with soft X-ray magnetic dichroisms |
| 260 | _ | _ | |a Amsterdam |c 2020 |b North-Holland Publ. Co. |
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| 520 | _ | _ | |a Polyoxopalladates hosting 3d, 4d or 4f central ions form a new class of molecular materials with well-defined, tunable morphology and ions coordination to be considered as model systems for basic research. We investigated the isotropic X-ray absorption near-edge structure (XANES), X-ray magnetic circular dichroism (XMCD), and X-ray magnetic linear dichroism (XMLD) to monitor the influence of symmetry changes on electronic and magnetic properties. After a brief introductory review about recent results on 3d and 4d transition metal ions, we (i) show that a change of the coordination symmetry from cubic eightfold (tetrahedral) to sixfold (octahedral) reduces the magnetic moment of Co2+ significantly and (ii) investigate whether axial distortions can modify the 4f states of trivalent lanthanide ions. While for Gd3+ there is no effect visible within experimental uncertainties, changes were observed for Dy3+ and Ho3+. The results are compared to atomic multiplet calculations including the intra-atomic spin-dipole term . Furthermore, several experimental pitfalls are discussed that may lead to misinterpretation of X-ray absorption data but can be excluded in the present study. |
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| 700 | 1 | _ | |a Schmitz, Detlef |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Shams, S. Fatemeh |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Siemensmeyer, Konrad |0 P:(DE-HGF)0 |b 6 |
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| 773 | _ | _ | |a 10.1016/j.jmmm.2020.167063 |g Vol. 514, p. 167063 - |0 PERI:(DE-600)1479000-2 |p 167063 - |t Journal of magnetism and magnetic materials |v 514 |y 2020 |x 0304-8853 |
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