000888201 001__ 888201
000888201 005__ 20210130010837.0
000888201 0247_ $$2doi$$a10.1016/j.apsusc.2019.144343
000888201 0247_ $$2ISSN$$a0169-4332
000888201 0247_ $$2ISSN$$a1873-5584
000888201 0247_ $$2Handle$$a2128/26439
000888201 0247_ $$2altmetric$$aaltmetric:69553861
000888201 0247_ $$2WOS$$aWOS:000502040600103
000888201 037__ $$aFZJ-2020-04755
000888201 082__ $$a660
000888201 1001_ $$0P:(DE-Juel1)176932$$aCojocariu, Iulia$$b0
000888201 245__ $$aEvaluation of molecular orbital symmetry via oxygen-induced charge transfer quenching at a metal-organic interface
000888201 260__ $$aAmsterdam$$bElsevier$$c2020
000888201 3367_ $$2DRIVER$$aarticle
000888201 3367_ $$2DataCite$$aOutput Types/Journal article
000888201 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1607520046_5502
000888201 3367_ $$2BibTeX$$aARTICLE
000888201 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000888201 3367_ $$00$$2EndNote$$aJournal Article
000888201 520__ $$aThin molecular films under model conditions are often exploited as benchmarks and case studies to investigate the electronic and structural changes occurring on the surface of metallic electrodes. Here we show that the modification of a metallic surface induced by oxygen adsorption allows the preservation of the geometry of a molecular adlayer, giving access to the determination of molecular orbital symmetries by means of near-edge X-ray absorption fine structure spectroscopy, NEXAFS. As a prototypical example, we exploited nickel tetraphenylporphyrin molecules deposited on a bare and on an oxygen pre-covered Cu(1 0 0) surface. We find that adsorbed atomic oxygen quenches the charge transfer at the metal-organic interface but, in contrast to a thin film sample, maintains the ordered adsorption geometry of the organic molecules. In this way, it is possible to disentangle π* and σ* symmetry orbitals, hence estimate the relative oscillator strength of core level transitions directly from the experimental data, as well as to evaluate and localize the degree of charge transfer in a coupled system. In particular, we neatly single out the σ* contribution associated with the N 1s transition to the mixed N 2px,y-Ni 3dx2-y2 orbital, which falls close to the leading π*-symmetry LUMO resonance.
000888201 536__ $$0G:(DE-HGF)POF3-522$$a522 - Controlling Spin-Based Phenomena (POF3-522)$$cPOF3-522$$fPOF III$$x0
000888201 588__ $$aDataset connected to CrossRef
000888201 7001_ $$0P:(DE-HGF)0$$aSturmeit, Henning Maximilian$$b1
000888201 7001_ $$0P:(DE-Juel1)162281$$aZamborlini, Giovanni$$b2
000888201 7001_ $$0P:(DE-HGF)0$$aCossaro, Albano$$b3
000888201 7001_ $$0P:(DE-HGF)0$$aVerdini, Alberto$$b4
000888201 7001_ $$00000-0001-8880-2080$$aFloreano, Luca$$b5
000888201 7001_ $$0P:(DE-HGF)0$$aD'Incecco, Enrico$$b6
000888201 7001_ $$0P:(DE-HGF)0$$aStredansky, Matus$$b7
000888201 7001_ $$0P:(DE-Juel1)169309$$aVesselli, Erik$$b8
000888201 7001_ $$0P:(DE-Juel1)169309$$aJugovac, Matteo$$b9
000888201 7001_ $$00000-0002-3654-3408$$aCinchetti, Mirko$$b10
000888201 7001_ $$0P:(DE-Juel1)145012$$aFeyer, Vitaliy$$b11$$eCorresponding author
000888201 7001_ $$0P:(DE-Juel1)130948$$aSchneider, Claus Michael$$b12
000888201 773__ $$0PERI:(DE-600)2002520-8$$a10.1016/j.apsusc.2019.144343$$gVol. 504, p. 144343 -$$p144343 -$$tApplied surface science$$v504$$x0169-4332$$y2020
000888201 8564_ $$uhttps://juser.fz-juelich.de/record/888201/files/1-s2.0-S0169433219331599-main.pdf$$yRestricted
000888201 8564_ $$uhttps://juser.fz-juelich.de/record/888201/files/1910.13910.pdf$$yPublished on 2019-10-23. Available in OpenAccess from 2021-10-23.
000888201 909CO $$ooai:juser.fz-juelich.de:888201$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000888201 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)176932$$aForschungszentrum Jülich$$b0$$kFZJ
000888201 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)145012$$aForschungszentrum Jülich$$b11$$kFZJ
000888201 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130948$$aForschungszentrum Jülich$$b12$$kFZJ
000888201 9131_ $$0G:(DE-HGF)POF3-522$$1G:(DE-HGF)POF3-520$$2G:(DE-HGF)POF3-500$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bKey Technologies$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vControlling Spin-Based Phenomena$$x0
000888201 9141_ $$y2020
000888201 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2020-09-15
000888201 915__ $$0LIC:(DE-HGF)CCBYNCND4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0
000888201 915__ $$0StatID:(DE-HGF)0530$$2StatID$$aEmbargoed OpenAccess
000888201 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bAPPL SURF SCI : 2018$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bAPPL SURF SCI : 2018$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-09-15
000888201 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2020-09-15$$wger
000888201 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-09-15
000888201 9201_ $$0I:(DE-Juel1)PGI-6-20110106$$kPGI-6$$lElektronische Eigenschaften$$x0
000888201 980__ $$ajournal
000888201 980__ $$aVDB
000888201 980__ $$aUNRESTRICTED
000888201 980__ $$aI:(DE-Juel1)PGI-6-20110106
000888201 9801_ $$aFullTexts