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024 7 _ |a 10.1103/PhysRevB.101.165422
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024 7 _ |a 2469-9950
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100 1 _ |a Haag, Norman
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245 _ _ |a Signatures of an atomic crystal in the band structure of a C 60 thin film
260 _ _ |a Woodbury, NY
|c 2020
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520 _ _ |a Transport phenomena in molecular materials are intrinsically linked to the orbital character and the degree of localization of the valence states. Here we combine angle-resolved photoemission with photoemission tomography to determine the spatial distribution of all molecular states of the valence band structure of a C60 thin film. While the two most frontier valence states exhibit a strong band dispersion, the states at larger binding energies are characterized by distinct emission patterns in energy and momentum space. Our findings demonstrate the formation of an atomic crystal-like band structure in a molecular solid with delocalized π-like valence states and strongly localized σ states at larger binding energies.
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542 _ _ |i 2020-04-21
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700 1 _ |a Lüftner, Daniel
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700 1 _ |a Haag, Florian
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700 1 _ |a Seidel, Johannes
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700 1 _ |a Kelly, Leah L.
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700 1 _ |a Zamborlini, Giovanni
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700 1 _ |a Jugovac, Matteo
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700 1 _ |a Feyer, Vitaliy
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700 1 _ |a Aeschlimann, Martin
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700 1 _ |a Puschnig, Peter
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700 1 _ |a Cinchetti, Mirko
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700 1 _ |a Stadtmüller, Benjamin
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773 _ _ |a 10.1103/PhysRevB.101.165422
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Marc 21