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@ARTICLE{Zinkevich:888399,
      author       = {Zinkevich, Tatiana and Fiedler, Andy and Guin, Marie and
                      Tietz, Frank and Guillon, Olivier and Ehrenberg, Helmut and
                      Indris, Sylvio},
      title        = {{N}a+ ion mobility in {N}a3+{S}c2({S}i{O}4) ({PO}4)3−
                      $(0.1 \< x \< 0.8)$ observed by 23{N}a {NMR}
                      spectroscopy},
      journal      = {Solid state ionics},
      volume       = {348},
      issn         = {0167-2738},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2020-04878},
      pages        = {115277},
      year         = {2020},
      abstract     = {The mobility of Na+ ions in Na3+xSc2(SiO4)x(PO4)3−x (0.1
                      < x < 0.8) was investigated by temperature-dependent 23Na
                      NMR spectroscopy and relaxometry. These measurements are
                      probing the local motion of the Na+ ions and give
                      information about the average hopping rate of the ions and
                      the activation barriers these ions have to overcome for
                      single jumps. The results are compared with those obtained
                      by impedance spectroscopy that is probing the long-range
                      transport of the Na+ ions. A consistent picture is obtained
                      with the fastest motion of the Na+ ions observed for the
                      sample with x = 0.4.},
      cin          = {IEK-1 / IEK-12},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000528485400014},
      doi          = {10.1016/j.ssi.2020.115277},
      url          = {https://juser.fz-juelich.de/record/888399},
}