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@ARTICLE{Kyrey:888506,
author = {Kyrey, Tetyana and Ganeva, Marina and Witte, Judith and von
Klitzing, Regine and Wellert, Stefan and Holderer, Olaf},
title = {{U}nderstanding near-surface polymer dynamics by a
combination of grazing-incidence neutron scattering and
virtual experiments},
journal = {Journal of applied crystallography},
volume = {54},
number = {1},
issn = {1600-5767},
address = {[S.l.]},
publisher = {Wiley-Blackwell},
reportid = {FZJ-2020-04970},
pages = {},
year = {2021},
abstract = {Neutron spin-echo spectroscopy is a unique experimental
method for the investigation of polymer dynamics. The
combination of neutron spin-echo spectroscopy with
grazing-incidence geometry (GINSES) opens the possibility to
probe the dynamics of soft-matter materials in the vicinity
of the solid substrate in the time range up to 100 ns.
However, the usage of the GINSES technique has some
peculiarities and, due to the novelty of the method and
complexity of the scattering geometry, difficulties in
further data analysis occur. The current work discusses how
virtual experiments within the distorted-wave Born
approximation using the BornAgain software can improve
GINSES data treatment and aid the understanding of polymer
dynamics in the vicinity of the solid surface. With two
examples, poly(N-isopropyl acrylamide) brushes and
poly(ethylene glycol) microgels on Si surfaces, the
simulation as well as the application of the simulation to
the GINSES data analysis are presented. The approach allowed
a deeper insight to be gained of the background effect and
scattering contribution of different layers.},
cin = {JCNS-FRM-II / JCNS-4 / JCNS-1 / MLZ},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-588b)4597118-3},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 623 - Data Management and Analysis (POF4-623) /
DFG project 290879244 - Grenzflächennahe Dynamik nicht
quervernetzter und quervernetzter Polymerarchitekturen auf
festen planaren Oberflächen},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-623 /
G:(GEPRIS)290879244},
experiment = {EXP:(DE-MLZ)J-NSE-20140101 / EXP:(DE-MLZ)SCG-20150203},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000613988600009},
doi = {10.1107/S1600576720014739},
url = {https://juser.fz-juelich.de/record/888506},
}