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@ARTICLE{Jansen:888556,
author = {Jansen, Marvin Marco and Perla, Pujitha and Kaladzhian,
Mane and von den Driesch, Nils and Janssen, Johanna and
Luysberg, Martina and Lepsa, Mihail I. and Grützmacher,
Detlev and Pawlis, Alexander},
title = {{P}hase-{P}ure {W}urtzite {G}a{A}s {N}anowires {G}rown by
{S}elf-{C}atalyzed {S}elective {A}rea {M}olecular {B}eam
{E}pitaxy for {A}dvanced {L}aser {D}evices and {Q}uantum
{D}isks},
journal = {ACS applied nano materials},
volume = {3},
number = {11},
issn = {2574-0970},
address = {Washington, DC},
publisher = {ACS Publications},
reportid = {FZJ-2020-05020},
pages = {11037 - 11047},
year = {2020},
abstract = {The control of the crystal phase in self-catalyzed
nanowires (NWs) is one of the central remaining open
challenges in the research field of III/V semiconductor NWs.
While several groups analyzed and revealed the growth
dynamics, no experimental growth scheme has been verified
yet, which reproducibly ensures the phase purity of binary
self-catalyzed grown NWs. Here, we demonstrate the advanced
control of self-catalyzed molecular beam epitaxy of GaAs NWs
with up to a grade of $100\%$ wurtzite (WZ) phase purity.
The evolution of the most important properties during the
growth, namely, the contact angle of the Ga droplet, the NW
length, and the diameter is analyzed by scanning electron
microscopy and transmission electron microscopy. Based on
these results, we developed a comprehensive NW growth model
for calculating the time-dependent evolution of the Ga
droplet contact angle. Using this model, the Ga flux was
dynamically modified during the growth to control and
stabilize the contact angle in a certain range favoring the
growth of phase-pure GaAs NWs. Although focusing on the
self-catalyzed growth of WZ GaAs NWs, our model is also
applicable to achieve phase-pure zinc blende (ZB) NWs and
can be easily generalized to other III/V compounds. The
self-catalyzed growth of such NWs may pave the way for
substantial improvement of GaAs NW laser devices, the
controlled growth of WZ/ZB quantum disks, and novel
heterostructured core/multishell NW systems with a pristine
crystalline order.},
cin = {PGI-9 / ER-C-1 / PGI-10},
ddc = {540},
cid = {I:(DE-Juel1)PGI-9-20110106 / I:(DE-Juel1)ER-C-1-20170209 /
I:(DE-Juel1)PGI-10-20170113},
pnm = {524 - Controlling Collective States (POF3-524) / 143 -
Controlling Configuration-Based Phenomena (POF3-143) / DFG
project 390534769 - EXC 2004: Materie und Licht für
Quanteninformation (ML4Q) (390534769) / DFG project
337456818 - Entwicklung von Spin-Qubit Bauelementen aus
ZnSe/},
pid = {G:(DE-HGF)POF3-524 / G:(DE-HGF)POF3-143 /
G:(GEPRIS)390534769 / G:(GEPRIS)337456818},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000595546500051},
doi = {10.1021/acsanm.0c02241},
url = {https://juser.fz-juelich.de/record/888556},
}