%0 Journal Article
%A Sarwar, Sidra
%A Sanz, Sergio
%A van Leusen, Jan
%A Nichol, Gary S.
%A Brechin, Euan K.
%A Kögerler, Paul
%T Phthalocyanine-polyoxotungstate lanthanide double deckers
%J Dalton transactions
%V 49
%N 46
%@ 1477-9234
%C London
%I Soc.
%M FZJ-2020-05108
%P 16638 - 16642
%D 2020
%X Acetate ligand metathesis results in the first hybrid [MIII(Pc)(PW11O39)]6− (M = Y, Dy, Tb) double-decker scaffolds, where a phthalocyanate (Pc2−) and one of the conceptually most simple polyoxotungstates, a monolacunary Keggin cluster, are interlinked via a single rare earth ion. Characterisation includes high-resolution mass spectrometry, synchrotron-based single-crystal X-ray diffraction, various spectroscopic and electrochemical methods, and magnetic studies revealing slow relaxation of the magnetisation for the Dy derivate.
%F PUB:(DE-HGF)16
%9 Journal Article
%$ 33169769
%U <Go to ISI:>//WOS:000597124500010
%R 10.1039/D0DT03716H
%U https://juser.fz-juelich.de/record/888673