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@ARTICLE{Sebastian:888730,
      author       = {Sebastian, Oshin and Nair, Sharanya and Taccardi, Nicola
                      and Wolf, Moritz and Søgaard, Alexander and Haumann, Marco
                      and Wasserscheid, Peter},
      title        = {{S}table and {S}elective {D}ehydrogenation of
                      {M}ethylcyclohexane using {S}upported {C}atalytically
                      {A}ctive {L}iquid {M}etal {S}olutions – {G}a 52
                      {P}t/{S}i{O} 2 {SCALMS}},
      journal      = {ChemCatChem},
      volume       = {12},
      number       = {18},
      issn         = {1867-3899},
      address      = {Weinheim},
      publisher    = {WILEY-VCH Verlag},
      reportid     = {FZJ-2020-05165},
      pages        = {4533 - 4537},
      year         = {2020},
      abstract     = {The use of gallium‐rich, Supported Catalytically Active
                      Liquid Metal Solution (SCALMS) is a promising new concept to
                      achieve catalysis with atomically dispersed active metal
                      atoms. Expanding our previous work on short alkane
                      dehydrogenation, we present here the application of SCALMS
                      for the dehydrogenation of methylcyclohexane (MCH) to
                      toluene (TOL) using a Ga52Pt alloy (liquid under reaction
                      conditions) supported on silica. Cycloalkane dehydrogenation
                      catalysis has attracted great attention recently in the
                      context of hydrogen storage concepts using liquid organic
                      hydrogen carrier (LOHC) systems. The system under
                      investigation showed high activity and stable conversion of
                      MCH at 450 °C and atmospheric pressure for more than
                      75 h time‐on‐stream $(XMCH=15 \%)$ with stable
                      toluene selectivity (STOL) of $85 \%.$ Compared to
                      commercially available Pt/SiO2, the SCALMS system resulted
                      in higher yields and robustness. Baseline experiments with
                      Pt‐free Ga/SiO2 under identical conditions revealed the
                      decisive influence of Pt dissolved in the liquid Ga matrix.},
      cin          = {IEK-11},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-11-20140314},
      pnm          = {113 - Methods and Concepts for Material Development
                      (POF3-113)},
      pid          = {G:(DE-HGF)POF3-113},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000568065200001},
      doi          = {10.1002/cctc.202000671},
      url          = {https://juser.fz-juelich.de/record/888730},
}