000888961 001__ 888961 000888961 005__ 20250701125839.0 000888961 0247_ $$2doi$$a10.1016/j.ijhydene.2021.01.232 000888961 0247_ $$2ISSN$$a0360-3199 000888961 0247_ $$2ISSN$$a1879-3487 000888961 0247_ $$2Handle$$a2128/28371 000888961 0247_ $$2WOS$$aWOS:000639330400012 000888961 037__ $$aFZJ-2020-05360 000888961 082__ $$a620 000888961 1001_ $$0P:(DE-Juel1)176715$$aRangel-Hernández, Victor$$b0$$eCorresponding author$$ufzj 000888961 245__ $$aAn Acoustic Emission Analysis of Glass-ceramic Sealants for Solid Oxide Fuel and Electrolysis Cells Exposed to Torsional Test: Room and High-temperature Experiments 000888961 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2021 000888961 3367_ $$2DRIVER$$aarticle 000888961 3367_ $$2DataCite$$aOutput Types/Journal article 000888961 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1627644409_3939 000888961 3367_ $$2BibTeX$$aARTICLE 000888961 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000888961 3367_ $$00$$2EndNote$$aJournal Article 000888961 520__ $$aThe mechanical integrity of the sealant material is of key importance for the long-term, reliable operation of solid oxide fuel/electrolysis cell stacks. However, in-situ monitoring and detection of potential failures in sealing materials using classical electrochemical characterization techniques are difficult tasks. Therefore, in this work, the acoustic emission (AE) technique is applied to monitor and characterize the failure process of a glass-ceramic sealant exposed to torsional shear strength at both room and typical stack operation temperature (750 °C). Hourglass-shaped steel specimens are produced for the tests. A glass-ceramic material with two different porosities is used to join the specimens. The failure process is characterized in terms of AE peak amplitude, AE cumulative hits and AE energy, as well as the average frequency content of the signals. The results indicate that the degree of microscopic damage can be determined from the analysis of the AE energy and the fracture mechanisms can be found by statistical analysis of the average frequency of the signals. The fractured surfaces are visualized by optical microscopy to unveil that specimens with high porosity showed a fully cohesive fracture pattern, while specimens with low porosity showed a partially fracture pattern. As a result, AE method promises to be a potential in-operando technique for monitoring mechanical failure processes inside solid oxide cell stacks. 000888961 536__ $$0G:(DE-HGF)POF4-1231$$a1231 - Electrochemistry for Hydrogen (POF4-123)$$cPOF4-123$$fPOF IV$$x0 000888961 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de 000888961 7001_ $$0P:(DE-Juel1)145945$$aFang, Qingping$$b1$$ufzj 000888961 7001_ $$0P:(DE-Juel1)129755$$aMalzbender, Jürgen$$b2$$ufzj 000888961 7001_ $$0P:(DE-HGF)0$$aSause, M. G. R.$$b3 000888961 7001_ $$0P:(DE-Juel1)161157$$aBabelot, Carole$$b4$$ufzj 000888961 7001_ $$0P:(DE-Juel1)133667$$aGross-Barsnick, Sonja-Michaela$$b5$$ufzj 000888961 7001_ $$0P:(DE-Juel1)129828$$aBlum, Ludger$$b6$$ufzj 000888961 773__ $$0PERI:(DE-600)1491915-1$$a10.1016/j.ijhydene.2021.01.232$$gVol. 46, no. 27, p. 14724 - 14734$$n27$$p14724 - 14734$$tJournal of power sources$$v46$$x0378-7753$$y2021 000888961 8564_ $$uhttps://juser.fz-juelich.de/record/888961/files/Rangel-Hernandez_Victor.pdf$$yPublished on 2021-02-23. 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