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@ARTICLE{Kuo:889015,
      author       = {Kuo, Mei-Tsan and Weber, Isabelle and Fittschen, Christa
                      and Vereecken, Luc and Lin, Jim Jr-Min},
      title        = {{K}inetics of dimethyl sulfide ({DMS}) reactions with
                      isoprene-derived {C}riegee intermediates studied with direct
                      {UV} absorption},
      journal      = {Atmospheric chemistry and physics},
      volume       = {20},
      number       = {21},
      issn         = {1680-7324},
      address      = {Katlenburg-Lindau},
      publisher    = {EGU},
      reportid     = {FZJ-2020-05389},
      pages        = {12983 - 12993},
      year         = {2020},
      abstract     = {Criegee intermediates (CIs) are formed in the ozonolysis of
                      unsaturated hydrocarbons and play a role in atmospheric
                      chemistry as a non-photolytic OH source or a strong oxidant.
                      Using a relative rate method in an ozonolysis experiment,
                      Newland et al. (2015) reported high reactivity of
                      isoprene-derived Criegee ntermediates towards dimethyl
                      sulfide (DMS) relative to that towards SO2 with the ratio of
                      the rate coefficients kDMS+CI/kSO2+CI = 3.5 ± 1.8.
                      Here we reinvestigated the kinetics of DMS reactions with
                      two major Criegee intermediates formed in isoprene
                      ozonolysis, CH2OO, and methyl vinyl ketone oxide (MVKO). The
                      individual CI was prepared following the reported photolytic
                      method with suitable (diiodo) precursors in the presence of
                      O2. The concentration of CH2OO or MVKO was monitored
                      directly in real time through their intense UV–visible
                      absorption. Our results indicate the reactions of DMS with
                      CH2OO and MVKO are both very slow; the upper limits of the
                      rate coefficients are 4 orders of magnitude smaller than the
                      rate coefficient reported by Newland et al. (2015) These
                      results suggest that the ozonolysis experiment could be
                      complicated such that interpretation should be careful and
                      these CIs would not oxidize atmospheric DMS at any
                      substantial level.},
      cin          = {IEK-8},
      ddc          = {550},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {243 - Tropospheric trace substances and their
                      transformation processes (POF3-243)},
      pid          = {G:(DE-HGF)POF3-243},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000587304600001},
      doi          = {10.5194/acp-20-12983-2020},
      url          = {https://juser.fz-juelich.de/record/889015},
}