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@ARTICLE{Kulvelis:889049,
      author       = {Kulvelis, Yu. V. and Primachenko, O. N. and Odinokov, A. S.
                      and Shvidchenko, A. V. and Bairamukov, V. Yu. and Gofman, I.
                      V. and Lebedev, V. T. and Ivanchev, S. S. and Vul, A. Ya.
                      and Kuklin, A. I. and Wu, Baohu},
      title        = {{C}omposite proton-conducting membranes with nanodiamonds},
      journal      = {Fullerenes, nanotubes $\&$ carbon nanostructures},
      volume       = {28},
      number       = {2},
      issn         = {1536-4046},
      address      = {London [u.a.]},
      publisher    = {Taylor $\&$ Francis},
      reportid     = {FZJ-2020-05417},
      pages        = {140 - 146},
      year         = {2020},
      abstract     = {A new approach was applied to improve the proton
                      conductivity mechanism in perfluorinated membranes for
                      hydrogen fuel cells. The composite short-side chain
                      membranes were modified with functionalized diamond
                      nanoparticles. Carboxylated nanodiamonds embedded in the
                      polymer matrix provide an increase in conductivity at a
                      moderate nanodiamond content, while the mechanical strength
                      of the membranes remains high. The casting method of
                      membranes preparation from solutions in
                      N,N-dimethylformamide allowed saving the general channel
                      structure in membranes at the presence of nanodiamonds, in
                      agreement with neutron scattering data. We propose the
                      formation of additional areas of conductivity, formed
                      controllably, due to nanodiamond particles associated with
                      polymer chains, on the surface of which accelerated
                      diffusion of protons through the hopping Grotthus mechanism
                      from the centers of proton adsorption proceeds with the
                      transition to proton-conducting channels of the matrix
                      covered with sulfonic groups.},
      cin          = {JCNS-4 / JCNS-1 / JCNS-FRM-II / MLZ},
      ddc          = {660},
      cid          = {I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-1-20110106 /
                      I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3},
      pnm          = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G4 /
                      G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000492306600001},
      doi          = {10.1080/1536383X.2019.1680981},
      url          = {https://juser.fz-juelich.de/record/889049},
}