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@ARTICLE{Zhang:889164,
author = {Zhang, Yuli and Tao, Mengchu and Zhang, Jinqiang and Liu,
Yi and Chen, Hongbin and Cai, Zhaonan and Konopka, Paul},
title = {{L}ong-term variations in ozone levels in the troposphere
and lower stratosphere over {B}eijing: observations and
model simulations},
journal = {Atmospheric chemistry and physics},
volume = {20},
number = {21},
issn = {1680-7324},
address = {Katlenburg-Lindau},
publisher = {EGU},
reportid = {FZJ-2021-00087},
pages = {13343 - 13354},
year = {2020},
abstract = {Tropospheric ozone is both a major pollutant and a
short-lived greenhouse gas and has therefore caused much
concern in recent years. The ozone profile in the
troposphere and lower stratosphere over Beijing has been
observed since 2002 by ozonesondes developed by the
Institute of Atmospheric Physics. Increasing concentrations
of tropospheric ozone from 2002 to 2010 measured by these
balloon-based observations have been reported previously. As
more observations are now available, we used these data to
analyse the long-term variability of ozone over Beijing
during the whole period from 2002 to 2018. The ozonesondes
measured increasing concentrations of ozone from 2002 to
2012 in both the troposphere and lower stratosphere. There
was a sudden decrease in observed ozone between 2011 and
2012. After this decrease, the increasing trend in ozone
concentrations slowed down, especially in the
mid-troposphere, where the positive trend became neutral. We
used the Chemical Lagrangian Model of the Stratosphere
(CLaMS) to determine the influence of the transport of ozone
from the stratosphere to the troposphere on the observed
ozone profiles. CLaMS showed a weak increase in the
contribution of stratospheric ozone before the decrease in
2011–2012 and a much more pronounced decrease after this
time. Because there is no tropospheric chemistry in CLaMS,
the sudden decrease simulated by CLaMS indicates that a
smaller downward transport of ozone from the stratosphere
after 2012 may explain a significant part of the observed
decrease in ozone in the mid-troposphere and lower
stratosphere. However, the influence of stratospheric ozone
in the lower troposphere is negligible in CLaMS, and the
hiatus in the positive trend after 2012 can be attributed to
a reduction in ozone precursors as a result of stronger
pollution control measures in Beijing.},
cin = {IEK-7},
ddc = {550},
cid = {I:(DE-Juel1)IEK-7-20101013},
pnm = {244 - Composition and dynamics of the upper troposphere and
middle atmosphere (POF3-244)},
pid = {G:(DE-HGF)POF3-244},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000588284300002},
doi = {10.5194/acp-20-13343-2020},
url = {https://juser.fz-juelich.de/record/889164},
}