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@INPROCEEDINGS{Rau:889170,
author = {Rau, Uwe},
title = {{P}hotovoltaic performance of metal-halide perovskites –
what is general and what is special?},
reportid = {FZJ-2021-00093},
year = {2020},
abstract = {After many decades of photovoltaic research we would expect
that there should be a common scientific understanding on
the necessary ingredients to make almost perfect solar
cells. However, the unprecedented success of metal-halide
perovskites (MHPs) stimulated discussions on whether there
could be a certain, yet non-established secret that
distinguishes this material from others. The present
contribution compares the performance of MHPs to other
photovoltaic materials in terms of a general top-down
approach. This direct comparison allows one to judge the
strengths and weaknesses of different technologies but also
gives some insight on the specific achievements, e.g. that,
on the one hand, the radiative yield of MHPs is second only
to the best GaAs solar cells, which implies open circuit
voltages that come close to the thermodynamic limits. On the
other hand the relative contribution of fill factor losses
to the overall efficiency losses in MHPs is relatively large
compared to most other technologies. Fill factor issues can
generally originate from recombination or voltage losses
during charge carrier collection, both aspects playing a
role for MHPs. This issue will be discussed in terms of new,
general models for the charge carrier separation in solar
cells. Finally, the question will be addressed whether
specific bulk properties of MHPs, like the presence of an
indirect band gap, the density of states, or small phonon
energies could be of importance for their favorable
photovoltaic behavior.},
month = {Nov},
date = {2020-11-27},
organization = {2020 MRS Virtual Spring/Fall Meeting
$\&$ Exhibit, virtual (USA), 27 Nov
2020 - 4 Dec 2020},
subtyp = {Invited},
cin = {IEK-5},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/889170},
}