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@ARTICLE{Liu:889212,
author = {Liu, Chang and Shviro, Meital and Gago, Aldo S. and
Zaccarine, Sarah F. and Bender, Guido and Gazdzicki, Pawel
and Morawietz, Tobias and Biswas, Indro and Rasinski, Marcin
and Everwand, Andreas and Schierholz, Roland and
Pfeilsticker, Jason and Müller, Martin and Lopes, Pietro P.
and Eichel, Rüdiger-A. and Pivovar, Bryan and Pylypenko,
Svitlana and Friedrich, K. Andreas and Lehnert, Werner and
Carmo, Marcelo},
title = {{E}xploring the {I}nterface of {S}kin‐{L}ayered
{T}itanium {F}ibers for {E}lectrochemical {W}ater
{S}plitting},
journal = {Advanced energy materials},
volume = {11},
number = {8},
issn = {1614-6840},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2021-00118},
pages = {2002926},
year = {2021},
abstract = {Water electrolysis is the key to a decarbonized energy
system, as it enables the conversion and storage of
renewably generated intermittent electricity in the form of
hydrogen. However, reliability challenges arising from
titanium‐based porous transport layers (PTLs) have
hitherto restricted the deployment of next‐generation
water‐splitting devices. Here, it is shown for the first
time how PTLs can be adapted so that their interface remains
well protected and resistant to corrosion across ≈4000 h
under real electrolysis conditions. It is also demonstrated
that the malfunctioning of unprotected PTLs is a result
triggered by additional fatal degradation mechanisms over
the anodic catalyst layer beyond the impacts expected from
iridium oxide stability. Now, superior durability and
efficiency in water electrolyzers can be achieved over
extended periods of operation with less‐expensive PTLs
with proper protection, which can be explained by the
detailed reconstruction of the interface between the
different elements, materials, layers, and components
presented in this work.},
cin = {IEK-14 / IEK-9 / IEK-4},
ddc = {050},
cid = {I:(DE-Juel1)IEK-14-20191129 / I:(DE-Juel1)IEK-9-20110218 /
I:(DE-Juel1)IEK-4-20101013},
pnm = {134 - Plasma-Wand-Wechselwirkung (POF4-134) / 123 -
Chemische Energieträger (POF4-123)},
pid = {G:(DE-HGF)POF4-134 / G:(DE-HGF)POF4-123},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000604739000001},
doi = {10.1002/aenm.202002926},
url = {https://juser.fz-juelich.de/record/889212},
}