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@ARTICLE{Lennartz:889377,
author = {Lennartz, S. T. and Gauss, M. and von Hobe, Marc and
Marandino, C. A.},
title = {{M}onthly resolved modelled oceanic emissions of carbonyl
sulfide for the period 2000-2019},
journal = {Earth system science data discussions},
volume = {2020},
issn = {1866-3591},
address = {Bremerhaven},
publisher = {Copernics Publication},
reportid = {FZJ-2021-00260},
pages = {389},
year = {2020},
abstract = {Carbonyl sulfide (OCS) is the most abundant, long-lived
sulphur gas in the atmosphere and a major supplier of sulfur
to the stratospheric sulfate aerosol layer. The short-lived
gas carbon disulfide (CS2) is oxidized to OCS and
constitutes a major indirect source to the atmospheric OCS
budget. The atmospheric budget of OCS is not well
constrained due to a large missing source needed to
compensate for substantial evidence that was provided for
significantly higher sinks. Oceanic emissions are associated
with major uncertainties. Here we provide a first, monthly
resolved ocean emission inventory of both gases for the
period 2000–2019 (available at
https://doi.org/10.5281/zenodo.4297010) (Lennartz et al.,
2020a). Emissions are calculated with a numerical box model
(resolution 2.8° × 2.8° at equator, T42 grid) for the
surface mixed layer. We find that interannual variability in
OCS emissions is smaller than seasonal variability, and is
mainly driven by variations in chromophoric dissolved
organic matter (CDOM), which influences both photochemical
and light-independent production. A comparison with a global
database of more than 2500 measurements reveals overall good
agreement. Emissions of CS2 constitute a larger sulfur
source to the atmosphere than OCS, and equally show
interannual variability connected to variability of CDOM.
The emission estimate of CS2 is associated with higher
uncertainties, as process understanding of the marine
cycling of CS2 is incomplete. We encourage the use of the
data provided here as input for atmospheric modelling
studies to further assess the atmospheric OCS budget and the
role of OCS in climate.},
cin = {IEK-7},
ddc = {550},
cid = {I:(DE-Juel1)IEK-7-20101013},
pnm = {244 - Composition and dynamics of the upper troposphere and
middle atmosphere (POF3-244)},
pid = {G:(DE-HGF)POF3-244},
typ = {PUB:(DE-HGF)16},
doi = {10.5194/essd-2020-389},
url = {https://juser.fz-juelich.de/record/889377},
}