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@ARTICLE{Schfer:889654,
author = {Schäfer, Dominik and Janssen, Tomke and Fang, Qingping and
Mertens, Frank and Blum, Ludger},
title = {{S}ystem-supporting {O}peration of {S}olid-oxide
{E}lectrolysis {S}tacks},
journal = {Energies},
volume = {14},
number = {3},
issn = {1996-1073},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2021-00286},
pages = {544},
year = {2021},
abstract = {Flexible, system-oriented operating strategies are becoming
increasingly important in terms of achieving a
climate-neutral energy system transformation. Solid-oxide
electrolysis (SOEC) can play an important role in the
production of green synthesis gas from renewable energy in
the future. Therefore, it is important to investigate the
extent to which SOEC can be used flexibly and which feedback
effects and constraints must be taken into account. In this
study, we derived a specific load profile from an energy
turnaround scenario that supports the energy system. SOEC
short-stacks were operated and we investigated the impact
that the load profile has on electrical stack performance
and stack degradation as well as the product gas composition
by means of Fourier-transform infrared spectroscopy. The
stacks could follow the grid-related requirement profiles of
secondary control power and minute reserves very well with
transition times of less than two minutes per $25\%$ of
relative power. Only short-term disturbances of the H2/CO
ratio were observed during transitions due to the adjustment
of feed gases. No elevated degradation effects resulting
from flexible operation were apparent over 1300 h, although
other causes of degradation were present.},
cin = {IEK-14},
ddc = {620},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {135 - Fuel Cells (POF3-135) / 1231 - Electrochemistry for
Hydrogen (POF4-123) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-HGF)POF4-1231 /
G:(DE-Juel1)SOFC-20140602},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000615048000001},
doi = {10.3390/en14030544},
url = {https://juser.fz-juelich.de/record/889654},
}