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@ARTICLE{Zhang:889870,
author = {Zhang, Yuting and Figueroa-Miranda, Gabriela and Wu,
Changtong and Willbold, Dieter and Offenhäusser, Andreas
and Mayer, Dirk},
title = {{E}lectrochemical dual-aptamer biosensors based on
nanostructured multielectrode arrays for the detection of
neuronal biomarkers},
journal = {Nanoscale},
volume = {12},
number = {31},
issn = {2040-3372},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2021-00478},
pages = {16501 - 16513},
year = {2020},
note = {Kein Post-print verfügbar},
abstract = {Multielectrode arrays (MEAs) have been increasingly used
for the development of biosensors due to their capability to
record signals from multiple channels, fast mass transfer
rates, and high spatial resolution. Alzheimer's disease (AD)
is often associated with mitochondrial dysfunction, which is
closely related to reduced levels of adenosine triphosphate
(ATP). Therefore, simultaneous detection of ATP together
with amyloid-β oligomers (AβO), a reliable biomarker for
AD, can potentially advance the early detection of
Alzheimer's disease. In this work, a dual-aptamer modified
MEA chip was developed that consists of microelectrodes
modified with electrodeposited 3D nanostructures (3D-GMEs).
Electrodeposition methods, deposition potential, and
deposition time were systematically altered and the active
surface areas as well as the electrode morphologies were
characterized by cyclic voltammetry and scanning electron
microscopy. The nanostructured microelectrodes were
sequentially modified with AβO and ATP specific aptamer
receptors. To achieve the modification of different aptamer
receptors at different 3D-GMEs of the same MEA chip,
electrochemical cleaning was applied to individual 3D-GMEs.
Ferrocene labels were attached to the aptamer receptors to
enable amperometric signaling after target–aptamer
binding. The developed aptasensor showed a linear detection
range from 1 pM to 200 nM for the detection of AβO and from
0.01 nM to 1000 nM for the detection of ATP. Finally, ATP
and AβO were detected simultaneously in the same analyte
solution by the same sensor chip, which could support the
early detection of AD, provide comprehensive information
about the health status of the patient, and be helpful for
pathological studies of neurodegenerative diseases.},
cin = {IBI-7},
ddc = {600},
cid = {I:(DE-Juel1)IBI-7-20200312},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551)},
pid = {G:(DE-HGF)POF3-551},
typ = {PUB:(DE-HGF)16},
pubmed = {32729601},
UT = {WOS:000560178300009},
doi = {10.1039/D0NR03421E},
url = {https://juser.fz-juelich.de/record/889870},
}