000889968 001__ 889968 000889968 005__ 20240712113240.0 000889968 0247_ $$2doi$$a10.1016/j.jpowsour.2020.228682 000889968 0247_ $$2ISSN$$a0378-7753 000889968 0247_ $$2ISSN$$a1873-2755 000889968 0247_ $$2Handle$$a2128/27002 000889968 0247_ $$2altmetric$$aaltmetric:88025115 000889968 0247_ $$2WOS$$aWOS:000573641500001 000889968 037__ $$aFZJ-2021-00571 000889968 082__ $$a620 000889968 1001_ $$0P:(DE-HGF)0$$aRiedel, M.$$b0$$eCorresponding author 000889968 245__ $$aPressurized operation of solid oxide electrolysis stacks: An experimental comparison of the performance of 10-layer stacks with fuel electrode and electrolyte supported cell concepts 000889968 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2020 000889968 3367_ $$2DRIVER$$aarticle 000889968 3367_ $$2DataCite$$aOutput Types/Journal article 000889968 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1611572828_2888 000889968 3367_ $$2BibTeX$$aARTICLE 000889968 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000889968 3367_ $$00$$2EndNote$$aJournal Article 000889968 520__ $$aThe electrochemical behavior of two different types of planar 10-layer solid oxide cell (SOC) stacks with having either fuel electrode supported cells or electrolyte supported cells, are examined under steam, co- and CO2 electrolysis at elevated pressures of up to 8 bar. Experiments with steady-state and dynamically recorded U(i)-characteristics are performed in order to evaluate the performances over a wide temperature range and for different operating conditions. Furthermore, the influence of the operating pressure is quantified via the temperature and pressure dependency of the related ASR values of each stack. Impedance analysis is conducted in order to investigate the major differences and the pressure effect on the specific process resistances during steam and CO2 electrolysis.In case of the stack with fuel electrode supported cells, the ASR is found to decrease significantly at elevated pressure leading to an overall performance gain, whereas the stack with electrolyte supported cells shows a minor pressure effect. An impedance study shows that the diffusion and activation resistances are significantly affected when conducting CO2 instead of H2O electrolysis for both stack concepts. Furthermore, the pressure sensitivity is found to be more dominant during CO2 electrolysis than during pure steam electrolysis operation. 000889968 536__ $$0G:(DE-HGF)POF3-135$$a135 - Fuel Cells (POF3-135)$$cPOF3-135$$fPOF III$$x0 000889968 588__ $$aDataset connected to CrossRef 000889968 7001_ $$0P:(DE-HGF)0$$aHeddrich, M. P.$$b1 000889968 7001_ $$0P:(DE-HGF)0$$aAnsar, A.$$b2 000889968 7001_ $$0P:(DE-Juel1)145945$$aFang, Q.$$b3 000889968 7001_ $$0P:(DE-Juel1)129828$$aBlum, Ludger$$b4$$ufzj 000889968 7001_ $$0P:(DE-HGF)0$$aFriedrich, K. 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