% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Kerscher:890002, author = {Kerscher, Manuel and Klein, Tobias and Schulz, Peter S. and Veroutis, Emmanouil and Dürr, Stefan and Preuster, Patrick and Koller, Thomas M. and Rausch, Michael H. and Economou, Ioannis G. and Wasserscheid, Peter and Fröba, Andreas P.}, title = {{T}hermophysical properties of diphenylmethane and dicyclohexylmethane as a reference liquid organic hydrogen carrier system from experiments and molecular simulations}, journal = {International journal of hydrogen energy}, volume = {45}, number = {53}, issn = {0360-3199}, address = {New York, NY [u.a.]}, publisher = {Elsevier}, reportid = {FZJ-2021-00596}, pages = {28903 - 28919}, year = {2020}, abstract = {This work contributes to the characterization of the liquid organic hydrogen carrier (LOHC) system diphenylmethane/dicyclohexylmethane by the experimental determination and molecular simulation of the thermophysical properties of the dehydrogenated and fully hydrogenated compounds in a process-relevant temperature range of up to 623 K. Liquid density, liquid viscosity, surface tension and liquid self-diffusion coefficient data measured by vibrating-tube densimeters, surface light scattering, rotational viscometry and NMR spectroscopy are correlated and compared with available literature data which are mostly restricted to temperatures below 473 K. Furthermore, it is demonstrated that an L-OPLS force field (FF) modified in the present study outperforms commonly used FFs from literature in predicting the thermophysical properties of both substances by equilibrium molecular dynamics simulations.}, cin = {IEK-9 / IEK-11}, ddc = {620}, cid = {I:(DE-Juel1)IEK-9-20110218 / I:(DE-Juel1)IEK-11-20140314}, pnm = {131 - Electrochemical Storage (POF3-131)}, pid = {G:(DE-HGF)POF3-131}, typ = {PUB:(DE-HGF)16}, UT = {WOS:000579568300058}, doi = {10.1016/j.ijhydene.2020.07.261}, url = {https://juser.fz-juelich.de/record/890002}, }