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@ARTICLE{Sun:890020,
author = {Sun, Ying and Eikerling, Michael and Zhang, Jianbo and
Huang, Jun},
title = {{I}mpedance {M}odel of a {W}ater-{F}illed {P}t {N}anopore:
{I}nterfacial {C}harging and {C}hemisorption {E}ffects},
journal = {Journal of the Electrochemical Society},
volume = {167},
number = {6},
issn = {1945-7111},
address = {Bristol},
publisher = {IOP Publishing},
reportid = {FZJ-2021-00614},
pages = {066519 -},
year = {2020},
abstract = {The impedance response contains rich information about an
electrochemical system under investigation. Disentangling
this highly convoluted information requires physical models.
In this work, we develop a theoretical impedance model for a
water-filled Pt nanopore, as a representative element in
electrocatalytically active layers of polymer electrolyte
fuel cells or electrolysis cells. The model accounts for
double-layer charging, proton conduction and oxygen
transport in the pore as well as chemisorption and oxygen
reduction reaction at the Pt surface. It relaxes two widely
used assumptions, namely, electroneutrality in solution
phase and infinitely fast adsorption kinetics. Analytical
impedance expressions are obtained for different limiting
cases and impedance fingerprints of interfacial charging and
chemisorption effects are identified.},
cin = {IEK-13},
ddc = {660},
cid = {I:(DE-Juel1)IEK-13-20190226},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000527148100001},
doi = {10.1149/1945-7111/ab864a},
url = {https://juser.fz-juelich.de/record/890020},
}