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@ARTICLE{Stroyuk:890128,
author = {Stroyuk, Oleksandr and Raevskaya, Alexandra and Spranger,
Felix and Selyshchev, Oleksandr and Dzhagan, Volodymyr and
Solonenko, Dmytro and Gaponik, Nikolai and Zahn, Dietrich R.
T. and Eychmüller, Alexander},
title = {{M}ercury-indium-sulfide nanocrystals: {A} new member of
the family of ternary in based chalcogenides},
journal = {The journal of chemical physics},
volume = {151},
number = {14},
issn = {1089-7690},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2021-00717},
pages = {144701},
year = {2019},
abstract = {A general synthesis approach of aqueous glutathione-capped
ternary Ag-In-S, Cu-In-S, and Hg-In-Snanocrystals (NCs) is
introduced allowing the NC composition to be varied in a
broad range. TernaryHg-In-S (HIS) NCs are reported for the
first time and found to have the same tetragonal
chalcopyritemotif as Cu-In-S and Ag-In-S NCs, corroborated
by phonon spectra, while X-ray photoelectronspectroscopic
data indicate mercury to be present as Hg+ in the Hg-In-S
NCs. Colloidal HIS and Hg-InS/ZnS NCs showed little or no
variations of the spectral width of the photoluminescence
band uponNC size selection, temperature variation in a broad
range of 10-350 K, deposition of a ZnS shell, or
apost-synthesis annealing. All these observations are
similar to those reported earlier for Ag-In-S andAg-In-S/ZnS
NCs and allowed us to assume a general photoluminescence
mechanism for all threeternary compounds, based on the model
of radiative self-trapped exciton recombination.},
cin = {IEK-11},
ddc = {530},
cid = {I:(DE-Juel1)IEK-11-20140314},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113) / 530 - Science and Technology of Nanosystems
(POF3-500)},
pid = {G:(DE-HGF)POF3-113 / G:(DE-HGF)POF3-530},
typ = {PUB:(DE-HGF)16},
pubmed = {31615238},
UT = {WOS:000500356200037},
doi = {10.1063/1.5119991},
url = {https://juser.fz-juelich.de/record/890128},
}