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| 001 | 890128 | ||
| 005 | 20240709082110.0 | ||
| 024 | 7 | _ | |a 10.1063/1.5119991 |2 doi |
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| 024 | 7 | _ | |a 1089-7690 |2 ISSN |
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| 100 | 1 | _ | |a Stroyuk, Oleksandr |0 P:(DE-Juel1)178670 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Mercury-indium-sulfide nanocrystals: A new member of the family of ternary in based chalcogenides |
| 260 | _ | _ | |a Melville, NY |c 2019 |b American Institute of Physics |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a A general synthesis approach of aqueous glutathione-capped ternary Ag-In-S, Cu-In-S, and Hg-In-Snanocrystals (NCs) is introduced allowing the NC composition to be varied in a broad range. TernaryHg-In-S (HIS) NCs are reported for the first time and found to have the same tetragonal chalcopyritemotif as Cu-In-S and Ag-In-S NCs, corroborated by phonon spectra, while X-ray photoelectronspectroscopic data indicate mercury to be present as Hg+ in the Hg-In-S NCs. Colloidal HIS and Hg-InS/ZnS NCs showed little or no variations of the spectral width of the photoluminescence band uponNC size selection, temperature variation in a broad range of 10-350 K, deposition of a ZnS shell, or apost-synthesis annealing. All these observations are similar to those reported earlier for Ag-In-S andAg-In-S/ZnS NCs and allowed us to assume a general photoluminescence mechanism for all threeternary compounds, based on the model of radiative self-trapped exciton recombination. |
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| 700 | 1 | _ | |a Raevskaya, Alexandra |0 0000-0002-9225-1258 |b 1 |
| 700 | 1 | _ | |a Spranger, Felix |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Selyshchev, Oleksandr |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Dzhagan, Volodymyr |0 0000-0002-7839-9862 |b 4 |
| 700 | 1 | _ | |a Solonenko, Dmytro |0 0000-0002-1699-9344 |b 5 |
| 700 | 1 | _ | |a Gaponik, Nikolai |0 0000-0002-8827-2881 |b 6 |
| 700 | 1 | _ | |a Zahn, Dietrich R. T. |0 0000-0002-8455-4582 |b 7 |
| 700 | 1 | _ | |a Eychmüller, Alexander |0 0000-0001-9926-6279 |b 8 |
| 773 | _ | _ | |a 10.1063/1.5119991 |g Vol. 151, no. 14, p. 144701 - |0 PERI:(DE-600)1473050-9 |n 14 |p 144701 |t The journal of chemical physics |v 151 |y 2019 |x 1089-7690 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/890128/files/1.5119991.pdf |y Published on 2019-10-08. Available in OpenAccess from 2020-10-08. |
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