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@ARTICLE{Zeng:890183,
author = {Zeng, Linxiang and Chen, Shi and Forberich, Karen and
Brabec, Christoph J. and Mai, Yaohua and Guo, Fei},
title = {{C}ontrolling the crystallization dynamics of photovoltaic
perovskite layers on larger-area coatings},
journal = {Energy $\&$ environmental science},
volume = {13},
number = {12},
issn = {1754-5706},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2021-00772},
pages = {4666 - 4690},
year = {2020},
abstract = {As perovskite solar cells are highly efficient and already
meet the efficiency requirement for renewable
powergeneration, more attention is given to technological
barriers such as scalability and stability. In particular,
thelarge efficiency losses associated with upscaling
lab-scale devices to large-area modules represents one ofthe
major hurdles for commercialization. Given the essential
role of the perovskite films in the deviceperformance, it is
of critical importance to develop reliable crystallization
protocols to deposit high-qualityperovskite layers via
scalable methods. This review summarizes recent advances in
emerging crystallizationprotocols for the large-scale
deposition of perovskite thin films. The unique merits of
the well-developedcrystallization strategies, including
antisolvent, gas quenching, vacuum quenching, etc., are
carefully analyzedand discussed. We highlight that,
independent of the coating method, creating intermediate
phases todecouple the otherwise overlapped solution coating
and crystal growth is essential to realize
homogeneouscoatings of perovskite thin films. Strategies for
enhancing the crystal morphology of perovskite films
arepresented as well, which is vitally important to realize
reproducible manufacturing of large-area modules.
Thistutorial review assists the screening and development of
robust crystallization strategies for scalabledeposition of
high-quality perovskite films for photovoltaic
applications.},
cin = {IEK-11},
ddc = {690},
cid = {I:(DE-Juel1)IEK-11-20140314},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000599751100009},
doi = {10.1039/D0EE02575E},
url = {https://juser.fz-juelich.de/record/890183},
}