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@ARTICLE{Reshetenko:890255,
author = {Reshetenko, Tatyana and Kulikovsky, Andrei},
title = {{D}istribution of {R}elaxation {T}imes: {A} {T}ool for
{M}easuring {O}xygen {T}ransport {R}esistivity of a
{L}ow–{P}t {PEM} {F}uel {C}ell {C}athode},
journal = {Journal of the Electrochemical Society},
volume = {167},
number = {14},
issn = {1945-7111},
address = {Bristol},
publisher = {IOP Publishing},
reportid = {FZJ-2021-00839},
pages = {144505 -},
year = {2020},
abstract = {Oxygen transport resistivity of the cathode catalyst layer
in a low–Pt PEM fuel cell has been determined using two
methods: the first one is fitting of our recent
physics–based impedance model to the experimental
impedance spectra of the cell, and the second is calculation
of distribution of relaxation times (DRT) using the same
spectra. Comparison of the two methods shows that the DRT
peak with the characteristic frequency on the order of 500
to 1000 Hz describes oxygen transport in the open pore and
in Nafion film covering Pt/C agglomerates in the catalyst
layer. This result makes it possible using experimental
impedance spectroscopy and DRT calculation for routine
measurements of cathode transport resistivity in low–Pt
PEMFCs.},
cin = {IEK-14},
ddc = {660},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {135 - Fuel Cells (POF3-135)},
pid = {G:(DE-HGF)POF3-135},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000588360200001},
doi = {10.1149/1945-7111/abc10f},
url = {https://juser.fz-juelich.de/record/890255},
}