000890327 001__ 890327
000890327 005__ 20240712113117.0
000890327 0247_ $$2doi$$a10.1002/aenm.202003738
000890327 0247_ $$2ISSN$$a1614-6832
000890327 0247_ $$2ISSN$$a1614-6840
000890327 0247_ $$2Handle$$a2128/27749
000890327 0247_ $$2altmetric$$aaltmetric:99066124
000890327 0247_ $$2WOS$$aWOS:000612637200001
000890327 037__ $$aFZJ-2021-00893
000890327 082__ $$a050
000890327 1001_ $$0P:(DE-HGF)0$$aKlein, Sven$$b0
000890327 245__ $$aUnderstanding the Outstanding High‐Voltage Performance of NCM523||Graphite Lithium Ion Cells after Elimination of Ethylene Carbonate Solvent from Conventional Electrolyte
000890327 260__ $$aWeinheim$$bWiley-VCH$$c2021
000890327 3367_ $$2DRIVER$$aarticle
000890327 3367_ $$2DataCite$$aOutput Types/Journal article
000890327 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1620302758_24838
000890327 3367_ $$2BibTeX$$aARTICLE
000890327 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000890327 3367_ $$00$$2EndNote$$aJournal Article
000890327 520__ $$aThe increase of specific energy of current Li ion batteries via further increase of the cell voltage, for example, to 4.5 V is typically accompanied by a sudden and rapid capacity fade, known as “rollover” failure. This failure is the result of Li dendrite formation triggered in the course of electrode cross‐talk, that is, dissolution of transition metals (TMs) from the cathode and deposition on the anode. It is shown herein, that the elimination of ethylene carbonate (EC) from a state‐of‐the‐art electrolyte, that is, from 1.0 m LiPF6 in a 3:7 mixture of EC and ethyl methyl carbonate prevents this failure in high‐voltage LiNi0.5Co0.2Mn0.3O2||graphite cells, even without any electrolyte additives. While the oxidative stability on the cathode side is similar in both electrolytes, visible by a decomposition plateau at 5.5 V versus Li|Li+ during charge, the anode side in the EC‐free electrolyte reveals significantly less TM deposits and Li metal dendrites compared to the EC‐based electrolyte. The beneficial effect of EC‐free electrolytes is related to a significantly increased amount of degraded LiPF6 species, which effectively trap dissolved TMs and suppress the effect of detrimental cross‐talk, finally realizing rollover‐free performance under high voltage conditions.
000890327 536__ $$0G:(DE-HGF)POF4-122$$a122 - Elektrochemische Energiespeicherung (POF4-122)$$cPOF4-122$$fPOF IV$$x0
000890327 588__ $$aDataset connected to CrossRef
000890327 7001_ $$0P:(DE-HGF)0$$avan Wickeren, Stefan$$b1
000890327 7001_ $$0P:(DE-Juel1)187078$$aRöser, Stephan$$b2$$ufzj
000890327 7001_ $$0P:(DE-HGF)0$$aBärmann, Peer$$b3
000890327 7001_ $$0P:(DE-Juel1)171270$$aBorzutzki, Kristina$$b4$$ufzj
000890327 7001_ $$0P:(DE-HGF)0$$aHeidrich, Bastian$$b5
000890327 7001_ $$0P:(DE-HGF)0$$aBörner, Markus$$b6
000890327 7001_ $$0P:(DE-Juel1)166130$$aWinter, Martin$$b7$$eCorresponding author$$ufzj
000890327 7001_ $$0P:(DE-HGF)0$$aPlacke, Tobias$$b8
000890327 7001_ $$0P:(DE-Juel1)171865$$aKasnatscheew, Johannes$$b9$$eCorresponding author
000890327 773__ $$0PERI:(DE-600)2594556-7$$a10.1002/aenm.202003738$$gp. 2003738 -$$n14$$p2003738$$tAdvanced energy materials$$v11$$x1614-6840$$y2021
000890327 8564_ $$uhttps://juser.fz-juelich.de/record/890327/files/aenm.202003738.pdf$$yOpenAccess
000890327 8767_ $$d2021-01-29$$eHybrid-OA$$jDEAL$$lDEAL: Wiley
000890327 909CO $$ooai:juser.fz-juelich.de:890327$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC_DEAL$$popen_access$$popenaire
000890327 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)187078$$aForschungszentrum Jülich$$b2$$kFZJ
000890327 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)171270$$aForschungszentrum Jülich$$b4$$kFZJ
000890327 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166130$$aForschungszentrum Jülich$$b7$$kFZJ
000890327 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)171865$$aForschungszentrum Jülich$$b9$$kFZJ
000890327 9130_ $$0G:(DE-HGF)POF3-131$$1G:(DE-HGF)POF3-130$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lSpeicher und vernetzte Infrastrukturen$$vElectrochemical Storage$$x0
000890327 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
000890327 9141_ $$y2021
000890327 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2020-08-27
000890327 915__ $$0LIC:(DE-HGF)CCBYNCND4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0
000890327 915__ $$0StatID:(DE-HGF)9920$$2StatID$$aIF >= 20$$bADV ENERGY MATER : 2018$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV ENERGY MATER : 2018$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)3001$$2StatID$$aDEAL Wiley$$d2020-08-27$$wger
000890327 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000890327 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-08-27
000890327 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-08-27
000890327 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x0
000890327 9801_ $$aAPC
000890327 9801_ $$aFullTexts
000890327 980__ $$ajournal
000890327 980__ $$aVDB
000890327 980__ $$aUNRESTRICTED
000890327 980__ $$aI:(DE-Juel1)IEK-12-20141217
000890327 980__ $$aAPC
000890327 981__ $$aI:(DE-Juel1)IMD-4-20141217